TY  - JOUR
A1  - Rettinger, Klaus
A1  - Burschka, Christian
A1  - Scheeben, Peter
A1  - Fuchs, Heike
A1  - Mosandl, Armin
T1  - Chiral 2-alkylbranched acids, esters and alcohols.  Preparation and stereospecific flavour evaluation
N2  - Racemic 2-alkylbranched acids are transformed to diastereomeric derivatives with (S)-2-hydroxy-3-phenylpropionic acid-N-methylamide or (S)-(-)-l-phenylethylamine and separated by liquid chromatography to pure diastereoisomers, which are subsequently hydrolyzed to yield optically pure acids. Enantiomeric alcohols are generated by LiAlH4-reduction of the corresponding acids, esters are synthesized by different methods. The odour impression of the enantiomeric compounds is investigated.
KW  - Säure
KW  - Ester
KW  - Alkohol
KW  - 2-alkylbranched acids
KW  - esters and alcohols
KW  - flavour substances
KW  - chirality and odour
Y1  - 1991
UR  - https://opus.bibliothek.uni-wuerzburg.de/frontdoor/index/index/docId/4494
UR  - https://nbn-resolving.org/urn:nbn:de:bvb:20-opus-31898
ER  -