TY - INPR A1 - Schmidt, Uwe A1 - Fantuzzi, Felipe A1 - Arrowsmith, Merle A1 - Hermann, Alexander A1 - Prieschl, Dominic A1 - Rempel, Anna A1 - Engels, Bernd A1 - Braunschweig, Holger T1 - Tuneable reduction of cymantrenylboranes to diborenes or borylene-derived boratafulvenes T2 - Chemical Communications N2 - Whereas the reduction of N-heterocyclic carbene (NHC)-stabilised cymantrenyldibromoboranes, (NHC)BBr\(_2\)Cym, in benzene results in formation of the corresponding diborenes (NHC)\(_2\)B\(_2\)Cym\(_2\), a change of solvent to THF yields a borylene of the form (NHC)\(_2\)BCym, stabilised through its boratafulvene resonance form. KW - Borylene KW - Diborene KW - Boranes Y1 - 2020 UR - https://opus.bibliothek.uni-wuerzburg.de/frontdoor/index/index/docId/22214 UR - https://nbn-resolving.org/urn:nbn:de:bvb:20-opus-222149 ER -