TY  - JOUR
A1  - Burschka, Christian
A1  - Wieber, Markus
T1  - Eine pentagonal pyramidale Koordination des Bismuts. Kristallstruktur von Methylbismutbis(dietyldithiocarbonat)
T1  - A pentagonal pyramidal coordination of Bismut. Crystal structure of Methylbismuthbis(diethyldithiocar bamate)
N2  - The crystal structure of the title compound, recrystallized from ethanol, was solved by means of X-ray diffraction methods and could be refined to an R-value of 0.050 with 2126 reflections observed. In contrast to its behaviour in benzene solution, where the compound is monomerie, in the crystalline state dimerie units are formed by intermoleeular Bi-S-interactions. The bismuth atoms are coordinated in form of a slightly distorted pentagonal pyramid with the free electron pair presumably directed opposite the apical C-atom.
KW  - Chemie
Y1  - 1979
UR  - https://opus.bibliothek.uni-wuerzburg.de/frontdoor/index/index/docId/4407
UR  - https://nbn-resolving.org/urn:nbn:de:bvb:20-opus-46750
ER  -