TY  - JOUR
A1  - Bold, Kevin
A1  - Stolte, Matthias
A1  - Shoyama, Kazutaka
A1  - Krause, Ana‐Maria
A1  - Schmiedel, Alexander
A1  - Holzapfel, Marco
A1  - Lambert, Christoph
A1  - Würthner, Frank
T1  - Macrocyclic Donor‐Acceptor Dyads Composed of Oligothiophene Half‐Cycles and Perylene Bisimides
T2  - Chemistry – A European Journal
N2  - A series of donor‐acceptor (D−A) macrocyclic dyads consisting of an electron‐poor perylene bisimide (PBI) π‐scaffold bridged with electron‐rich α‐oligothiophenes bearing four, five, six and seven thiophene units between the two phenyl‐imide substituents has been synthesized and characterized by steady‐state UV/Vis absorption and fluorescence spectroscopy, cyclic and differential pulse voltammetry as well as transient absorption spectroscopy. Tying the oligothiophene strands in a conformationally fixed macrocyclic arrangement leads to a more rigid π‐scaffold with vibronic fine structure in the respective absorption spectra. Electrochemical analysis disclosed charged state properties in solution which are strongly dependent on the degree of rigidification within the individual macrocycle. Investigation of the excited state dynamics revealed an oligothiophene bridge size‐dependent fast charge transfer process for the macrocyclic dyads upon PBI subunit excitation.
KW  - donor-acceptor dyad
KW  - macrocycle
KW  - oligothiophene
KW  - perylene bisimide
KW  - photoinduced electron transfer
Y1  - 2022
UR  - https://opus.bibliothek.uni-wuerzburg.de/frontdoor/index/index/docId/27643
UR  - https://nbn-resolving.org/urn:nbn:de:bvb:20-opus-276435
VL  - 28
IS  - 30
ER  -