TY  - INPR
A1  - Arrowsmith, Merle
A1  - Böhnke, Julian
A1  - Braunschweig, Holger
A1  - Deißenberger, Andrea
A1  - Dewhurst, Rian
A1  - Ewing, William
A1  - Hörl, Christian
A1  - Mies, Jan
A1  - Muessig, Jonas
T1  - Simple Solution-Phase Syntheses of Tetrahalodiboranes(4) and their Labile Dimethylsulfide Adducts
T2  - Chemical Communications
N2  - Convenient, solution-phase syntheses of tetrahalodiboranes(4) B\(_2\)F\(_4\), B\(_2\)Cl\(_4\) and B\(_2\)I\(_4\) are presented herein from common precursor B\(_2\)Br\(_4\). In addition, the dimethylsulfide adducts B\(_2\)Cl\(_4\)(SMe\(_2\))\(_2\) and B\(_2\)Br\(_4\)(SMe\(_2\))\(_2\) are conveniently prepared in one-step syntheses from the commercially-available starting material B\(_2\)(NMe\(_2\))\(_4\). The results provide simple access to the full range of tetrahalodiboranes(4) for the exploration of their untapped synthetic potential.
KW  - Boron
KW  - Diboranes
KW  - Tetrafluorodiborane
Y1  - 2017
UR  - https://opus.bibliothek.uni-wuerzburg.de/frontdoor/index/index/docId/14943
UR  - https://nbn-resolving.org/urn:nbn:de:bvb:20-opus-149438
N1  - This is the pre-peer reviewed version of the following article: Chemical Communications, 2017,53, 8265-8267, which has been published in final form at doi:10.1039/C7CC03148C.
VL  - 53
ER  -