TY  - JOUR
A1  - Gärtner, Annalena
A1  - Marek, Matthäus
A1  - Arrowsmith, Merle
A1  - Auerhammer, Dominic
A1  - Radacki, Krzysztof
A1  - Prieschl, Dominic
A1  - Dewhurst, Rian D.
A1  - Braunschweig, Holger
T1  - Boron- versus Nitrogen-Centered Nucleophilic Reactivity of (Cyano)hydroboryl Anions: Synthesis of Cyano(hydro)organoboranes and 2-Aza-1,4-diborabutatrienes
T2  - Chemistry—A European Journal
N2  - Cyclic alkyl(amino)carbene-stabilized (cyano)hydroboryl anions were synthesized by deprotonation of (cyano)dihydroborane precursors. While they display boron-centered nucleophilic reactivity towards organohalides, generating fully unsymmetrically substituted cyano(hydro)organoboranes, they show cyano-nitrogen-centered nucleophilic reactivity towards haloboranes, resulting in the formation of hitherto unknown linear 2-aza-1,4-diborabutatrienes.
KW  - nucleophile
KW  - boron
KW  - boryl anion
KW  - cumulene
Y1  - 2021
UR  - https://opus.bibliothek.uni-wuerzburg.de/frontdoor/index/index/docId/25685
UR  - https://nbn-resolving.org/urn:nbn:de:bvb:20-opus-256853
VL  - 27
IS  - 37
ER  -