@article{SuRajeshkumarXiangetal.2022,
  author    = {Su, Wei and Rajeshkumar, Thayalan and Xiang, Libo and Maron, Laurent and Ye, Qing},
  title     = {Facile Synthesis of Uranium Complexes with a Pendant Borane Lewis Acid and 1,2-Insertion of CO into a U-N Bond},
  series = {Angewandte Chemie International Edition},
  volume    = {61},
  journal   = {Angewandte Chemie International Edition},
  number    = {51},
  doi       = {10.1002/anie.202212823},
  url       = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-312197},
  year      = {2022},
  abstract  = {In this contribution, we illustrate uranium complexes bearing a pendant borate (i.e. 1 and 2) or a pendant borane (i.e. 3 and 4) moiety via reaction of the highly strained uranacycle I with various 3-coordinate boranes. Complexes 3 and 4 represent the first examples of uranium complexes with a pendant borane Lewis acid. Moreover, complex 3 was capable of activation of CO, delivering a new CO activation mode, and an abnormal CO 1,2-insertion pathway into a U-N bond. The importance of the pendant borane moiety was confirmed by the controlled experiments.},
  language  = {en}
}
@unpublished{SchmidtFantuzziArrowsmithetal.2020,
  author    = {Schmidt, Uwe and Fantuzzi, Felipe and Arrowsmith, Merle and Hermann, Alexander and Prieschl, Dominic and Rempel, Anna and Engels, Bernd and Braunschweig, Holger},
  title     = {Tuneable reduction of cymantrenylboranes to diborenes or borylene-derived boratafulvenes},
  series = {Chemical Communications},
  journal   = {Chemical Communications},
  doi       = {10.1039/D0CC06398C},
  url       = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-222149},
  year      = {2020},
  abstract  = {Whereas the reduction of N-heterocyclic carbene (NHC)-stabilised cymantrenyldibromoboranes, (NHC)BBr\(_2\)Cym, in benzene results in formation of the corresponding diborenes (NHC)\(_2\)B\(_2\)Cym\(_2\), a change of solvent to THF yields a borylene of the form (NHC)\(_2\)BCym, stabilised through its boratafulvene resonance form.},
  language  = {en}
}