@article{ArnoldBraunschweigDamme2012, author = {Arnold, Nicole and Braunschweig, Holger and Damme, Alexander}, title = {Bis(μ-diisopropyl-phosphanido-\(κ^2\)P:P)bis-[hydrido(triisopropyl-phosphane-κP)platinum(II)]}, series = {Acta crystallographica. Section E, Structure reports online}, volume = {E68}, journal = {Acta crystallographica. Section E, Structure reports online}, doi = {http://dx.doi.org/10.1107/S1600536812022829}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-123723}, pages = {m808}, year = {2012}, abstract = {In the centrosymmetric molecular structure of the title compound \([Pt_2(C_6H_{14}P)_2H_2)(C_9H_{21}P)_2]\), each \(Pt^{II}\) atom is bound on one side to a phosphane ligand \((PiPr_3)\) and a hydrido ligand. On the other side, it is bound to two phosphanide ligands \((μ-PiPr_2)\), which engage a bridging position between the two \(Pt^{II}\) atoms, forming a distorted square-planar structure motif. The PtPt distance is 3.6755(2){\AA}. A comparable molecular structure was observed for bis-(μ-di-tert-butyl-phosphanido)bis-[hydrido(triethyl-phosphane)platinum(II)] [Itazaki et al. (2004 ). Organometallics, 23, 1610-1621].}, language = {en} } @article{Gessner2012, author = {Gessner, Viktoria H.}, title = {Diphenyl[2-(phenyl-sulfon-yl)propan-2-yl]-\(\lambda^5\)-phosphanethione}, series = {Acta crystallographica. Section E, Structure reports online}, volume = {E68}, journal = {Acta crystallographica. Section E, Structure reports online}, number = {o1045}, doi = {10.1107/S1600536812010082}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-123635}, year = {2012}, abstract = {The title compound, \(C_{21}H_{21}O_2PS_2\), was obtained from the corresponding dilithio methandiide by treatment with iodo-methane. The bond lengths and angles deviate considerably from those in the dimetallated compound. These differences are most pronounced in the PCS backbone. While the title compound features C-P and C-S distances of 1.9082(17) and 1.8348(17){\AA}, respectively, the dianion showed \(C-P_{av}\) distances shortened by 11\% [1.710(4){\AA}] and C-S distances shortened by 12\% [1.614(3){\AA}]. Additionally, the P-C-S angle experiences a contraction by methyl-ation of the dianion from 121.4(2) to 111.96(9)° in the title compound.}, language = {en} } @article{FinzeReissFrohn2012, author = {Finze, Maik and Reiss, Guido J. and Frohn, Hermann-Josef}, title = {2,3,5,6-Tetrafluoro-1,4-bis(trimethylsilyl)benzene}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-75401}, year = {2012}, abstract = {no abstract available}, subject = {Chemie}, language = {en} } @article{FinzeReiss2012, author = {Finze, Maik and Reiss, Guido J.}, title = {Trimethyl­sulfonium 1-amino-6-fluoro-2,3,4,5,7,8,9,10,11,12-decaiodo-1-carba-closo-dodeca­borate}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-75397}, year = {2012}, abstract = {no abstract available}, subject = {Chemie}, language = {en} } @article{BraunschweigArnoldGruss2011, author = {Braunschweig, Holger and Arnold, Thomas and Gruss, Katrin}, title = {cyclo-Tri-mu-oxido-tris{[(eta 5,eta 5)-1,2-bis(cyclopentadienyl)-1,1,2,2-tetramethyldisilane]zirconium(IV)}: atrimeric disila-bridged oxidozirconocene}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-74737}, year = {2011}, abstract = {no abstract available}, subject = {Chemie}, language = {en} }