@article{TackeLangeBentlage1982, author = {Tacke, Reinhold and Lange, H. and Bentlage, A.}, title = {Synthese und Eigenschaften von (Hydroxy-methyl)diorganylsilanen}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-63727}, year = {1982}, abstract = {The synthesis of the (hydroxymethyl)diorganylsilanes R\(^1\)R\(^2\)Si(H)CH\(_2\)OH (4a: R\(^1\) = R\(^2\) = CH\(_3\), 2-silaisobutanol; 4b: R\(^1\) = CH\(_3\), R\(^2\) == C\(_6\)H\(_5\); 4c: R\(^1\) == R\(^2\) = C\(_6\)H\(_5\))is achieved bythereactionof R\(^1\)R\(^2\)Si(Cl)CH\(_2\)Cl (2a-c) with AcOH/NEt\(_3\) to R\(^1\)R\(^2\)Si(OAc)CH\(_2\)OAc (Ja-c), followed by treating with LiAlH\(_4\) and hydrolysis.}, subject = {Anorganische Chemie}, language = {de} }