@article{FergerBergerRauchetal.2021,
  author    = {Ferger, Matthias and Berger, Sarina M. and Rauch, Florian and Sch{\"o}nitz, Markus and R{\"u}he, Jessica and Krebs, Johannes and Friedrich, Alexandra and Marder, Todd B.},
  title     = {Synthesis of Highly Functionalizable Symmetrically and Unsymmetrically Substituted Triarylboranes from Bench-Stable Boron Precursors},
  series = {Chemistry—A European Journal},
  volume    = {27},
  journal   = {Chemistry—A European Journal},
  number    = {35},
  doi       = {10.1002/chem.202100632},
  url       = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-256827},
  pages     = {9094-9101},
  year      = {2021},
  abstract  = {A novel and convenient methodology for the one-pot synthesis of sterically congested triarylboranes by using bench-stable aryltrifluoroborates as the boron source is reported. This procedure gives systematic access to symmetrically and unsymmetrically substituted triarylboranes of the types BAr\(_{2}\)Ar' and BArAr'Ar'', respectively. Three unsymmetrically substituted triarylboranes as well as their iridium-catalyzed C-H borylation products are reported. These borylated triarylboranes contain one to three positions that can subsequently be orthogonally functionalized in follow-up reactions, such as Suzuki-Miyaura cross-couplings or Sonogashira couplings.},
  language  = {en}
}
@unpublished{BraunschweigBruecknerDeissenbergeretal.2017,
  author    = {Braunschweig, Holger and Br{\"u}ckner, Tobias and Deißenberger, Andrea and Dewhurst, Rian and Gackstatter, Annika and G{\"a}rtner, Annalena and Hofmann, Alexander and Kupfer, Thomas and Prieschl, Dominic and Thiess, Torsten and Wang, Sunewang Rixin},
  title     = {Reaction of Dihalodiboranes(4) with N-Heterocyclic Silylenes: Facile Construction of 1-Aryl-2-Silyl-1,2-Diboraindanes},
  series = {Chemistry, A European Journal},
  journal   = {Chemistry, A European Journal},
  doi       = {10.1002/chem.201702377},
  url       = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-153068},
  year      = {2017},
  abstract  = {Dihalodiboranes(4) react with an N-heterocyclic silylene (NHSi) to generate NHSi-adducts of 1-aryl-2-silyl-1,2-diboraindanes as confirmed by X-ray crystallography, featuring the functionalization of both B-X (X = halogen) bonds and a C-H bond under mild conditions. Coordination of a third NHSi to the proposed 1,1-diaryl- 2,2-disilyldiborane(4) intermediates, generated by a two-fold B-X insertion, may be crucial for the C-H borylation that leads to the final products. Notably, our results demonstrate the first C-H borylation with a strong B-F bond activated by silylene insertion.},
  language  = {en}
}
@article{BergerFergerMarder2021,
  author    = {Berger, Sarina M. and Ferger, Matthias and Marder, Todd B.},
  title     = {Synthetic Approaches to Triarylboranes from 1885 to 2020},
  series = {Chemistry - A European Journal},
  volume    = {27},
  journal   = {Chemistry - A European Journal},
  number    = {24},
  doi       = {10.1002/chem.202005302},
  url       = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-238952},
  pages     = {7043 -- 7058},
  year      = {2021},
  abstract  = {In recent years, research in the fields of optoelectronics, anion sensors and bioimaging agents have been greatly influenced by novel compounds containing triarylborane motifs. Such compounds possess an empty p-orbital at boron which results in useful optical and electronic properties. Such a diversity of applications was not expected when the first triarylborane was reported in 1885. Synthetic approaches to triarylboranes underwent various changes over the following century, some of which are still used in the present day, such as the generally applicable routes developed by Krause et al. in 1922, or by Grisdale et al. in 1972 at Eastman Kodak. Some other developments were not pursued further after their initial reports, such as the synthesis of two triarylboranes bearing three different aromatic groups by Mikhailov et al. in 1958. This review summarizes the development of synthetic approaches to triarylboranes from their first report nearly 135 years ago to the present.},
  language  = {en}
}