@article{KarGehrigAllampallyetal.2016,
  author    = {Kar, Haridas and Gehrig, Dominik W. and Allampally, Naveen Kumar and Fern{\´a}ndez, Gustavo and Laquai, Fr{\´e}d{\´e}ric and Ghosh, Suhrit},
  title     = {Cooperative supramolecular polymerization of an amine-substituted naphthalene-diimide and its impact on excited state photophysical properties},
  series = {Chemical Science},
  volume    = {7},
  journal   = {Chemical Science},
  number    = {2},
  doi       = {10.1039/c5sc03462k},
  url       = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-191459},
  pages     = {1115-1120},
  year      = {2016},
  abstract  = {A donor-acceptor-donor (D-A-D) type naphthalene-diimide (NDI-H) chromophore exhibits highly cooperative J-aggregation leading to nanotubular self-assembly and gelation in n-decane, as demonstrated by UV/Vis, FT-IR, photoluminescence and microscopy studies. Analysis of temperature-dependent UV/Vis spectra using the nucleation-elongation model and FT-IR data reveals the molecular origin of the cooperative nature of the self-assembly. The supramolecular polymerization is initiated by H-bonding up to a degree of polymerization similar to 20-25, which in a subsequent elongation step promotes J-aggregation in orthogonal direction leading to possibly a sheet-like structure that eventually produces nanotubes. Time-resolved fluorescence and absorption measurements demonstrate that such a tubular assembly enables very effective delocalization of excited states resulting in a remarkably prolonged excited state lifetime.},
  language  = {en}
}
@article{TurkinHolzapfelAgarwaletal.2021,
  author    = {Turkin, Arthur and Holzapfel, Marco and Agarwal, Mohit and Fischermeier, David and Mitric, Roland and Schweins, Ralf and Gr{\"o}hns, Franziska and Lambert, Christoph},
  title     = {Solvent Induced Helix Folding of Defined Indolenine Squaraine Oligomers},
  series = {Chemistry—A European Journal},
  volume    = {27},
  journal   = {Chemistry—A European Journal},
  number    = {32},
  doi       = {10.1002/chem.202101063},
  url       = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-256869},
  pages     = {8380-8389},
  year      = {2021},
  abstract  = {A protecting group strategy was employed to synthesise a series of indolenine squaraine dye oligomers up to the nonamer. The longer oligomers show a distinct solvent dependence of the absorption spectra, that is, either a strong blue shift or a strong red shift of the lowest energy bands in the near infrared spectral region. This behaviour is explained by exciton coupling theory as being due to H- or J-type coupling of transition moments. The H-type coupling is a consequence of a helix folding in solvents with a small Hansen dispersity index. DOSY NMR, small angle neutron scattering (SANS), quantum chemical and force field calculations agree upon a helix structure with an unusually large pitch and open voids that are filled with solvent molecules, thereby forming a kind of clathrate. The thermodynamic parameters of the folding process were determined by temperature dependent optical absorption spectra.},
  language  = {en}
}