@unpublished{ArrowsmithBoehnkeBraunschweigetal.2017, author = {Arrowsmith, Merle and B{\"o}hnke, Julian and Braunschweig, Holger and Deißenberger, Andrea and Dewhurst, Rian and Ewing, William and H{\"o}rl, Christian and Mies, Jan and Muessig, Jonas}, title = {Simple Solution-Phase Syntheses of Tetrahalodiboranes(4) and their Labile Dimethylsulfide Adducts}, series = {Chemical Communications}, volume = {53}, journal = {Chemical Communications}, doi = {10.1039/C7CC03148C}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-149438}, pages = {8265-8267}, year = {2017}, abstract = {Convenient, solution-phase syntheses of tetrahalodiboranes(4) B\(_2\)F\(_4\), B\(_2\)Cl\(_4\) and B\(_2\)I\(_4\) are presented herein from common precursor B\(_2\)Br\(_4\). In addition, the dimethylsulfide adducts B\(_2\)Cl\(_4\)(SMe\(_2\))\(_2\) and B\(_2\)Br\(_4\)(SMe\(_2\))\(_2\) are conveniently prepared in one-step syntheses from the commercially-available starting material B\(_2\)(NMe\(_2\))\(_4\). The results provide simple access to the full range of tetrahalodiboranes(4) for the exploration of their untapped synthetic potential.}, language = {en} } @unpublished{ArrowsmithBraunschweigStennett2017, author = {Arrowsmith, Merle and Braunschweig, Holger and Stennett, Tom}, title = {Formation and Reactivity of Electron-Precise B-B Single and Multiple Bonds}, series = {Angewandte Chemie, International Edition}, volume = {56}, journal = {Angewandte Chemie, International Edition}, number = {1}, doi = {10.1002/anie.201610072}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-145631}, pages = {96-115}, year = {2017}, abstract = {Recent years have seen rapid advances in the chemistry of small molecules containing electron-precise boron-boron bonds. This review provides an overview of the latest methods for the controlled synthesis of B-B single and multiple bonds as well as the ever-expanding range of reactivity displayed by the latter.}, language = {en} }