@phdthesis{Duerrbeck2013,
  author    = {D{\"u}rrbeck, Nina},
  title     = {Photoinduced Charge-Transfer Processes in Redox Cascades based on Triarylamine Donors and the Perchlorinated Triphenylmethyl Radical Acceptor},
  url       = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-90078},
  school      = {Universit{\"a}t W{\"u}rzburg},
  year      = {2013},
  abstract  = {In this work, a series of redox cascades was synthesised and investigated in view of their photophysical and electrochemical properties. The cascades are based on a perchlorinated triphenylmethyl radical acceptor and two triarylamine donors. Absorption spectra showed the presence of charge-transfer bands in the NIR range of the spectra, which pointed to the population of a charge-transfer state between a triarylamine donor and the radical acceptor. A weak to moderate emission in the NIR range of the spectra was observed for all compounds in cyclohexane. Spectroelectrochemical measurements were used to investigate the characteristic spectral features of the oxidised and reduced species of all compounds. Transient absorption spectra in the ns- and fs-time regime revealed an additional hole transfer in the cascades between the triarylamine donors, resulting in a charge-separated state. Charge-separation and -recombination processes were found to be located in the ps-time regime.},
  subject      = {Ladungstransfer},
  language  = {en}
}