@article{HausoelKarolakŞaşιoğluetal.2017,
  author    = {Hausoel, A. and Karolak, M. and Şa{\c{s}}ιoğlu, E. and Lichtenstein, A. and Held, K. and Katanin, A. and Toschi, A. and Sangiovanni, G.},
  title     = {Local magnetic moments in iron and nickel at ambient and Earth's core conditions},
  series = {Nature Communications},
  volume    = {8},
  journal   = {Nature Communications},
  number    = {16062},
  doi       = {10.1038/ncomms16062},
  url       = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-170681},
  year      = {2017},
  abstract  = {Some Bravais lattices have a particular geometry that can slow down the motion of Bloch electrons by pre-localization due to the band-structure properties. Another known source of electronic localization in solids is the Coulomb repulsion in partially filled d or f orbitals, which leads to the formation of local magnetic moments. The combination of these two effects is usually considered of little relevance to strongly correlated materials. Here we show that it represents, instead, the underlying physical mechanism in two of the most important ferromagnets: nickel and iron. In nickel, the van Hove singularity has an unexpected impact on the magnetism. As a result, the electron-electron scattering rate is linear in temperature, in violation of the conventional Landau theory of metals. This is true even at Earth's core pressures, at which iron is instead a good Fermi liquid. The importance of nickel in models of geomagnetism may have therefore to be reconsidered.},
  language  = {en}
}
@article{KuegelKarolakKroenleinetal.2018,
  author    = {K{\"u}gel, Jens and Karolak, Michael and Kr{\"o}nlein, Andreas and Serrate, David and Bode, Matthias and Sangiovanni, Giorgio},
  title     = {Reversible magnetic switching of high-spin molecules on a giant Rashba surface},
  series = {npj Quantum Materials},
  volume    = {3},
  journal   = {npj Quantum Materials},
  doi       = {10.1038/s41535-018-0126-z},
  url       = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-230866},
  year      = {2018},
  abstract  = {The quantum mechanical screening of a spin via conduction electrons depends sensitively on the environment seen by the magnetic impurity. A high degree of responsiveness can be obtained with metal complexes, as the embedding of a metal ion into an organic molecule prevents intercalation or alloying and allows for a good control by an appropriate choice of the ligands. There are therefore hopes to reach an "on demand" control of the spin state of single molecules adsorbed on substrates. Hitherto one route was to rely on "switchable" molecules with intrinsic bistabilities triggered by external stimuli, such as temperature or light, or on the controlled dosing of chemicals to form reversible bonds. However, these methods constrain the functionality to switchable molecules or depend on access to atoms or molecules. Here, we present a way to induce bistability also in a planar molecule by making use of the environment. We found that the particular "habitat" offered by an antiphase boundary of the Rashba system BiAg2 stabilizes a second structure for manganese phthalocyanine molecules, in which the central Mn ion moves out of the molecular plane. This corresponds to the formation of a large magnetic moment and a concomitant change of the ground state with respect to the conventional adsorption site. The reversible spin switch found here shows how we can not only rearrange electronic levels or lift orbital degeneracies via the substrate, but even sway the effects of many-body interactions in single molecules by acting on their surrounding.},
  language  = {en}
}