@article{KimChristlKochl1990, author = {Kim, E. and Christl, Manfred and Kochl, J. K.}, title = {Charge-Transfer Cycloaddition of Homobenzvalene with Tetracyanoethylene}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58537}, year = {1990}, abstract = {The transient yellow color observed in the cycloaddition of homobenzvalene (HB) with tetracyanoethylene (TCNE) is associated with the charge-transfer complex [HB, TCNE). The deliberate photoexcitation of [HB,TCNE) affords a mixture of charge-transfer cycloadducts (1, 2, and 3) that differs from that obtained in thermal cycloaddition. The relationship of {HB t TCNE•) radical-ion pair (as the critical reactive intermediate in charge-transfer cycloaddition) to the activation process for thermal cycloaddition is discussed.}, subject = {Organische Chemie}, language = {en} }