@article{ChristlTuerkPetersetal.1994, author = {Christl, Manfred and T{\"u}rk, M. and Peters, K. and Peters, E.-M. and Schnering, H. G. von}, title = {Octahydro-1,2,3:4,5,6-dimethenopentalen-2-carbonitril, das erste Derivat eines noch unbekannten (CH)\(_{10}\)-Kohlenwasserstoffs}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58728}, year = {1994}, abstract = {No abstract available}, subject = {Organische Chemie}, language = {de} } @article{ChristlTuerkPetersetal.1994, author = {Christl, Manfred and T{\"u}rk, M. and Peters, K. and Peters, E.-M. and Schnering, H. G. von}, title = {Octahydro-1,2,3:4,5,6-dimethenopentalene-2-carbonitrile, the First Derivative of a Yet-Unknown (CH)\(_{10}\)-Hydrocarbon}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58731}, year = {1994}, abstract = {No abstract available}, subject = {Organische Chemie}, language = {en} } @article{BentleyChristlKemmeretal.1994, author = {Bentley, T. W. and Christl, Manfred and Kemmer, R. and Llewellyn, G. and Oakley, J. E.}, title = {Kinetic and Spectroscopic Characterisation of Highly Reactive Methanesulfonates. Leaving Group Effects for Solvolyses and Comments on Geminal Electronic Effects Influencing S\(_N\)1 Reactivity}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58748}, year = {1994}, abstract = {Highly reactive methanesulfonates (mesylates, ROMs) have been prepared from 1-phenylethanol. cyclohex-2-en-1-ol, diphenylmethanol and p-methoxybenzyl alcohol by treatment with methanesulfonyl chloride and triethylamine in dichloro- or trichloro-methane at - 20 to 0 °C. The mesylates. characterised in solution by \(^1\)H and \(^{13}\)C NMR at -20 °C, were obtained in satisfactory purity (ca. 95\%) in cold solutions but they decomposed by reaction with chloride, triethylamine or the parent alcohol. Rate constants for solvolyses in aqueous acetone and aqueous ethanol have been determined by a fast response conductimetric method. Product selectivities for solvolyses of pmethoxybenzyl mesylate in aqueous ethanol and methanol at 0 °C have been determined by HPLC. From additional new or Iiterature kinetic data for solvolyses of corresponding bromides. chlorides and p-nitrobenzoates (OPNB). Br/CI. OMs/Br and OMs/OPNB rate ratios were calculated; the results are consistent with electronic effects stabilising the carbocationic transition states and increasing OMs/Br rate ratios for these SN 1 solvolyses; none of the evidence supports a geminal electronic effect on Br/CI rate ratios (e.g. caused by stabilisation of the initial state in pmethoxybenzyl chloride). Steric effects on ester /halide rate ratios for solvolyses of tertiary substrates are confirmed. Relative rates over a 10\(^{16}\) range for ester and halide leaving groups are evaluated for solvolyses of 1-phenylethyl substrates in 80\% ethanol-water. updating previous work by Noyce et al. (1972).}, subject = {Organische Chemie}, language = {en} } @article{ChristlGerstnerKemmeretal.1994, author = {Christl, Manfred and Gerstner, E. and Kemmer, R. and Llewellyn, G. and Bentley, T. W.}, title = {Elektrophile Additionen an das Bicyclo[1.1.0]butan-System von 1-Phenyl- und 1-(4-Anisyl)tricyclo[4.1.0.0\(^{2,7}\)]heptan: S{\"a}ure-katalysierte Reaktionen mit Wasser und Methanol, Anlagerung von Essigs{\"a}ure und Oxymercurierung}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58696}, year = {1994}, abstract = {No abstract available}, subject = {Organische Chemie}, language = {de} } @article{GerstnerKemmerChristl1994, author = {Gerstner, E. and Kemmer, R. and Christl, Manfred}, title = {Elektrophile Additionen an das Bicyclo[1.1.0]butan-System von Tricyclo[4.1.0.0\(^{2,7}\)]-heptan-Derivaten: Halogen-Elektrophile}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58700}, year = {1994}, abstract = {No abstract available}, subject = {Organische Chemie}, language = {de} } @article{ChristlBraunWolzetal.1994, author = {Christl, Manfred and Braun, Martin and Wolz, E. and Wagner, W.}, title = {Cycloallene, 9 - 1-Phenyl-1-aza-3,4-cyclohexadien, das erste Isodihydropyridin: Erzeugung und Abfangreaktionen}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58714}, year = {1994}, abstract = {No abstract available}, subject = {Organische Chemie}, language = {de} } @article{ChristlLanzendoerferGroetschetal.1993, author = {Christl, Manfred and Lanzend{\"o}rfer, U. and Gr{\"o}tsch, M. M. and Hegmann, J. and Ditterich, E. and H{\"u}ttner, G. and Peters, K. and Peters, E.-M. and Schnering, H. G. von}, title = {Cycloadditionen von 6H-1,3,4-0xadiazin-6-onen (4,5-Diaza-α-pyronen), 12 - Dieckmann-Kondensationen ohne Basen}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58665}, year = {1993}, abstract = {No abstract available}, subject = {Organische Chemie}, language = {de} } @article{FeineisSchwarzHegmannetal.1993, author = {Feineis, E. and Schwarz, H. and Hegmann, J. and Christl, Manfred and Peters, K. and Peters, E.-M. and Schnering, H. G. von}, title = {Cycloadditionen von 6H-1,3,4-0xadiazin-6-onen (4,5-Diaza-α-pyronen), 13 - Diels-Alder-Reaktionen mit 6H-1,3,4-Oxadiazin-6-onen als Dienophil}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58673}, year = {1993}, abstract = {No abstract available}, subject = {Organische Chemie}, language = {de} } @article{BentleyNormanGerstneretal.1993, author = {Bentley, T. W. and Norman, S. J. and Gerstner, E. and Kemmer, R. and Christl, Manfred}, title = {Solvolysis of Tricyclo[3.1.0.0\(^{2,6}\)]hex-3-yl and Bicyclo[2.1.1]hex-2-yl Sulfonates}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58689}, year = {1993}, abstract = {No abstract available}, subject = {Organische Chemie}, language = {en} } @article{ChristlMueller1993, author = {Christl, Manfred and M{\"u}ller, H.}, title = {Induktiver Effekt, negative Hyperkonjugation und Gegenion sind nicht die Ursache der besonderen Eigenschaften des Bicyclo[3.2.1]octa-3,6-dien-2-yl-Anions. - Eine NMR-Studie mit phenylsubstituierten Modellen}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58655}, year = {1993}, abstract = {No abstract available}, subject = {Organische Chemie}, language = {de} } @article{StanglJelinekFinkChristl1992, author = {Stangl, R. and Jelinek-Fink, H. and Christl, Manfred}, title = {Darstellung phenylsubstituierter Derivate des Tricyclo[4.1.0.0\(^{2,7}\)]heptans und des 1,2,3,4-Tetrahydro-1,2,3-methenonaphthalins}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58610}, year = {1992}, abstract = {No abstract available}, subject = {Organische Chemie}, language = {de} } @article{ChristlStanglJelinekFink1992, author = {Christl, Manfred and Stangl, R. and Jelinek-Fink, H.}, title = {Zur Kenntnis der thermischen Umlagerung des Bicyclo[1.1.0]butan-Systems. Eine kinetische Studie des {\"U}bergangs von Tricyclo[4.1.0.0\(^{2,7}\)]heptanen in Bicyclo[3.2.0]hept-6-ene}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58623}, year = {1992}, abstract = {No abstract available}, subject = {Organische Chemie}, language = {de} } @article{ChristlBraunMueller1992, author = {Christl, Manfred and Braun, Martin and M{\"u}ller, Germar}, title = {1,2,4-Cyclohexatriene, an Isobenzene, and Bicyclo[4.4.0)deca-1,3,5,7,8-pentaene, an Isonaphthalene: Generation and Trapping Reactions}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58639}, year = {1992}, abstract = {No abstract available}, subject = {Organische Chemie}, language = {en} } @article{HegmannDitterichHuettneretal.1992, author = {Hegmann, J. and Ditterich, E. and H{\"u}ttner, G. and Christl, Manfred and Peters, K. and Peters, E.-M. and Schnering, H. G. von}, title = {δ-Chlor-δ-lactone aus γ-Oxoketenen}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58649}, year = {1992}, abstract = {No abstract available}, subject = {Organische Chemie}, language = {de} } @article{ReuchleinKraftChristletal.1991, author = {Reuchlein, H. and Kraft, A. and Christl, Manfred and Peters, K. and Peters, E.-M. and Schnering, H. G. von}, title = {Reaktionen von Bicyclo[2.1.1]hexenen mit 1,3,4-Oxadiazin-6-onen und dynamische Effekte einem in neungliedrigen, {\"u}berbr{\"u}ckten, α,β-unges{\"a}ttigten Enollacton}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58577}, year = {1991}, abstract = {No abstract available}, subject = {Organische Chemie}, language = {de} } @article{MarkgrafCortDavisetal.1991, author = {Markgraf, J. H. and Cort, J. R. and Davis, H. A. and Lindeman, N. I. and Myers, C. R. and Kraft, A. and Christl, Manfred}, title = {Strained Heterocyclic Systems. 20. Basicities of Bicyclic Quinoxalines}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58584}, year = {1991}, abstract = {No abstract available}, subject = {Organische Chemie}, language = {en} } @article{BentleyChristlNorman1991, author = {Bentley, T. W. and Christl, Manfred and Norman, S. J.}, title = {Methanesulfonate/p-Nitrobenzoate and p-Toluenesulfonate/p-Nitrobenzoate Rate Ratios. Solvolyses of 1-Adamantyl and Benzhydryl Substrates}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58599}, year = {1991}, abstract = {No abstract available}, subject = {Organische Chemie}, language = {en} } @article{JelinekFinkChristlPetersetal.1991, author = {Jelinek-Fink, H. and Christl, Manfred and Peters, K. and Peters, E.-M. and Schnering, H. G. von}, title = {Cycloallene, 7 : Ein Siebenringallen-Dimer: Darstellung aus einem 7,7-Dibromnorcaran-Derivat und Thermolyse}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58603}, year = {1991}, abstract = {No abstract available}, subject = {Organische Chemie}, language = {de} } @article{KimChristlKochl1990, author = {Kim, E. and Christl, Manfred and Kochl, J. K.}, title = {Charge-Transfer Cycloaddition of Homobenzvalene with Tetracyanoethylene}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58537}, year = {1990}, abstract = {The transient yellow color observed in the cycloaddition of homobenzvalene (HB) with tetracyanoethylene (TCNE) is associated with the charge-transfer complex [HB, TCNE). The deliberate photoexcitation of [HB,TCNE) affords a mixture of charge-transfer cycloadducts (1, 2, and 3) that differs from that obtained in thermal cycloaddition. The relationship of {HB t TCNE•) radical-ion pair (as the critical reactive intermediate in charge-transfer cycloaddition) to the activation process for thermal cycloaddition is discussed.}, subject = {Organische Chemie}, language = {en} } @article{LangHerzogStangletal.1990, author = {Lang, R. and Herzog, C. and Stangl, R. and Brunn, E. and Braun, M. and Christl, Manfred and Peters, K. and Peters, E.-M. and Schnering, H. G. von}, title = {Reaktionen von Homobenzvalenen mit 4-Phenyl-3H-1,2,4-triazol-3,5(4H)-dion, Tetracyanethylen, Chlorsulfonylisocyanat und Schwefeldioxid. Einige konzertierte 1,4-Additionen an eine Vinylcyclopropan-Einheit}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58527}, year = {1990}, abstract = {No abstract available}, subject = {Organische Chemie}, language = {de} }