@phdthesis{Rehm2015, author = {Rehm, Stefanie}, title = {Spermine-functionalized Perylene Bisimide Dyes: Synthesis and Self-assembly in Water}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-123201}, school = {Universit{\"a}t W{\"u}rzburg}, year = {2015}, abstract = {The main objective of this thesis was the design and synthesis of perylene bisimide dyes with sufficient water-solubility for the construction of self-assembled architectures in aqueous solutions. Beside these tasks another goal of this project was the control over the self-assembly process in terms of aggregate size and helicity, respectively. Within this thesis an appropriate synthesis for spermine-functionalized perylene bisimide dyes was developed and conducted successfully. The characterization of these building blocks and their course of self-assembly were investigated by NMR, UV/Vis and fluorescence spectroscopy as well as by atomic force and transmission electron microscopy. For the better understanding of the experimental results theoretical calculations were performed.}, subject = {Perylenderivate}, language = {en} }