@article{HagspielArrowsmithFantuzzietal.2021, author = {Hagspiel, Stephan and Arrowsmith, Merle and Fantuzzi, Felipe and Vargas, Alfredo and Rempel, Anna and Hermann, Alexander and Br{\"u}ckner, Tobias and Braunschweig, Holger}, title = {Highly colored boron-doped thiazolothiazoles from the reductive dimerization of boron isothiocyanates}, series = {Angewandte Chemie International Edition}, volume = {60}, journal = {Angewandte Chemie International Edition}, number = {12}, doi = {10.1002/anie.202015508}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-256432}, pages = {6446-6450}, year = {2021}, abstract = {Reduction of (CAAC)BBr\(_2\)(NCS) (CAAC=cyclic alkyl(amino)carbene) in the presence of a Lewis base L yields tricoordinate (CAAC)LB(NCS) borylenes which undergo reversible E/Z-isomerization. The same reduction in the absence of L yields deep blue, bis(CAAC)-stabilized, boron-doped, aromatic thiazolothiazoles resulting from the dimerization of dicoordinate (CAAC)B(NCS) borylene intermediates.}, language = {en} }