@phdthesis{Wehner2021,
  author    = {Wehner, Marius},
  title     = {Supramolecular Polymorphism in Homo- and Heterochiral Supramolecular Polymerizations},
  doi       = {10.25972/OPUS-21151},
  url       = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-211519},
  school      = {Universit{\"a}t W{\"u}rzburg},
  year      = {2021},
  abstract  = {The aim of the first part of this thesis was to investigate (R,R)-PBI as a model system for polymorphism at its origin by a supramolecular approach. The pathway complexity of (R,R)-PBI was fine-tuned by experimental parameters such as solvent, temperature and concentration to make several supramolecular polymorphs accessible. Mechanistic and quantum chemical studies on the kinetics and thermodynamics of the supramolecular polymerization of (R,R)-PBI were conducted to shed light on the initial stages of polymorphism. The second part of this work deals with mechanistic investigations on the supramolecular polymerization of the racemic mixture of (R,R)- and (S,S)-PBI with regard to homochiral and heterochiral aggregation leading to conglomerates and a racemic supramolecular polymer, respectively.},
  subject      = {Supramolekulare Chemie},
  language  = {en}
}