@article{ChristlBrunn1981, author = {Christl, Manfred and Brunn, E.}, title = {Tetracyclo[4.1.0.0\(^{2,4}\).0\(^{3,5}\)]heptane aus 7,8-Diazatetracyclo[4.3.0.0\(^{2,4}\).0\(^{3,5}\)]non-7-enen}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58094}, year = {1981}, abstract = {No abstract available}, subject = {Organische Chemie}, language = {de} } @article{ChristlLechner1982, author = {Christl, Manfred and Lechner, M.}, title = {Einige Reaktionen des 8,8-Dibromtetracyclo[5.1.0.0\(^{2,4}\).0\(^{3,5}\)]octans}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58108}, year = {1982}, abstract = {No abstract available}, subject = {Organische Chemie}, language = {de} } @article{ChristlLang1982, author = {Christl, Manfred and Lang, R.}, title = {Tricyclo[5.1.0.0\(^{2,8}\)]octa-3,5-diene (Octavalene)}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58124}, year = {1982}, abstract = {No abstract available}, subject = {Organische Chemie}, language = {en} } @article{ChristlFreundHennebergeretal.1988, author = {Christl, Manfred and Freund, S. and Henneberger, H. and Kraft, A. and Hauck, J. and Irngartinger, H.}, title = {Several Polycyclic Valence Isomers of Dimethyl [14]Annulene-1,8-dicarboxylate. Reactivity of a "Nonconjugated" Bis(bicyclo[1.1.0]butane)}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58413}, year = {1988}, abstract = {Diels-Alder reaction of dimethyl 1,2,4,5-tetrazine-3,6-dicarboxylate (5) with benzvalene (4), norbornene, and norbornadiene afforded the azo compounds 7 and 8. Theseare derivatives of 2,3-diazabicyclo[2.2.2]oct-2-ene as is azo compound 3, which had been obtained previously from 5 and 2 equiv of benzvalene (4). The photochemical extrusion of nitrogen from 3, 7, and 8 has been studied. Whereas 7 and 8 on direct irradiation in benzene gave rise exclusively to the bicyclo[2.2.0]hexane derivatives 9 and 10, respectively, from 3 in addition to the bicyclo[2.2.0]hexane 11, the diolefin 1l was formed. Diolefin 12 has cisdouble bonds in the nine-membered ring and is fixed in a boat conformation in a manner so that the two bicyclobutane systems approach each other very closely. This geometry suggests the unusual ring opening of the intermediate 1,4-cyclohexanediyl diradical from a boat conformation, which arises by inversion of the primarily generated boat conformation. Sensitized photolysis of 3 as weilasthat of ll produced the saturated isomer 13 of 11 and 12. The proximity of the bicyclobutane systems in 1l causes unprecedented reactions leading to cage compounds. When ll was heated at 90 °C, a rearrangement to the pentacyclic product 10 took place. Utilization of tetradeuteriated substrate ll-d4 supported a pathway with two diradical intermediates. Behaving in a convcntional manncr, bicyclobutane 9 and bis(bicyclobutane) 11 took up 1 and 2 equiv of thiophenol most probably in a radical-chain addition to give the thioethers 28 and 19, respectively. In contrast, bis(bicyclobutane) ll was converted by 1 equiv of thiophenol into cagc compound 30 in a process involving both the strained a systems. Heating at 80 °C subjected 30 to a reversible Copc rearrangement, resulting in a 6:1 mixture of 31 and 30. When it was treated with bromine, 11 was transformed to cage compound 38. This addition is believed to proceed via a cationic intermediate. The structure of cage compound 10 was established by a singlc-crystal X-ray analysis of dialcohol 11 prepared from 20 and methyllithium.}, subject = {Organische Chemie}, language = {en} } @article{ChristlLanzendoerferHegmannetal.1985, author = {Christl, Manfred and Lanzend{\"o}rfer, F. and Hegmann, J. and Peters, K. and Peters, E.-M. and Schnering, H. G. von}, title = {Cycloadditionen von 6-0xo-l,3,4-oxadiazinen (4,5-Diaza-α-pyronen), 3 : Reaktionen von 6-Oxo-2,5-diaryl-1,3,4-oxadiazinen mit Alkenen}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58191}, year = {1985}, abstract = {Das bekannte 6-0xo-2,5-diphenyl-6H-l,3,4-oxadiazin (1 a) und die neuen 2,5-Diarylderivate 1 b - g lagern Alkene an, und es entstehen stickstofIfreie Produkte. Im Falle von Cyclopropenen und Cyclobuten bilden sich die a,p-unges{\"a}ttigten Siebenring-Enollactone 42 -45 bzw. das a,ß-unges{\"a}ttigte Achtring-Enollacton 47. 42a und d erleiden an basischem Aluminiumoxid die H-Verschiebung zu den ß,y-unges{\"a}ttigten Siebenring-Enollactonen 46a bzw. d. Bei weiteren Olefinen wurden die 'Y-Ketoketene des Typs 33 als Zwischenprodukte nachgewiesen oder sind aufgrund der Konstitution der Endprodukte wahrscheinlich. Aus 1 a werden mit Norbomen, Norbornadien, Cyc1openten, trans-Cycloocten und Styrol die Sechsring-Enollactone 10, 13, 15, 19 bzw. 21 und 22 erhalten. 10 isomerisiert mit Kalium-tert-butoxid zu 34, und die Methanolyse dieser Enollactone erbringt die diastereomeren Methy]ester 12 bzw. 35. Das y-Ketoketen 16 aus trans-Cycloocten nimmt schneller Wasser und Methanol zu 17 bzw. 18 auf als es zum Enollacton 19 cyclisiert. cis,trans-l,5-Cyc1ooctadien erbringt {\"u}ber die Stufe des nachgewiesenen y-Ketoketens 40 in einer intramolekularen [2 + 2J-Cyc1oaddition den Tricyclus 41. Tetracyclische Verbindungen des Typs 4 gehen aus der Umsetzung von Benzvalen (2) mit 1 hervor. Durch R{\"o}ntgenstrukturanalysen wurden Konstitution und Konfiguration von 10, 19 und 41 aufgekl{\"a}rt}, subject = {Organische Chemie}, language = {de} } @article{BentleyChristlNorman1991, author = {Bentley, T. W. and Christl, Manfred and Norman, S. J.}, title = {Methanesulfonate/p-Nitrobenzoate and p-Toluenesulfonate/p-Nitrobenzoate Rate Ratios. Solvolyses of 1-Adamantyl and Benzhydryl Substrates}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58599}, year = {1991}, abstract = {No abstract available}, subject = {Organische Chemie}, language = {en} } @article{JelinekFinkChristlPetersetal.1991, author = {Jelinek-Fink, H. and Christl, Manfred and Peters, K. and Peters, E.-M. and Schnering, H. G. von}, title = {Cycloallene, 7 : Ein Siebenringallen-Dimer: Darstellung aus einem 7,7-Dibromnorcaran-Derivat und Thermolyse}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58603}, year = {1991}, abstract = {No abstract available}, subject = {Organische Chemie}, language = {de} } @article{StanglJelinekFinkChristl1992, author = {Stangl, R. and Jelinek-Fink, H. and Christl, Manfred}, title = {Darstellung phenylsubstituierter Derivate des Tricyclo[4.1.0.0\(^{2,7}\)]heptans und des 1,2,3,4-Tetrahydro-1,2,3-methenonaphthalins}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58610}, year = {1992}, abstract = {No abstract available}, subject = {Organische Chemie}, language = {de} } @article{ChristlStanglJelinekFink1992, author = {Christl, Manfred and Stangl, R. and Jelinek-Fink, H.}, title = {Zur Kenntnis der thermischen Umlagerung des Bicyclo[1.1.0]butan-Systems. Eine kinetische Studie des {\"U}bergangs von Tricyclo[4.1.0.0\(^{2,7}\)]heptanen in Bicyclo[3.2.0]hept-6-ene}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58623}, year = {1992}, abstract = {No abstract available}, subject = {Organische Chemie}, language = {de} } @article{ChristlBraunMueller1992, author = {Christl, Manfred and Braun, Martin and M{\"u}ller, Germar}, title = {1,2,4-Cyclohexatriene, an Isobenzene, and Bicyclo[4.4.0)deca-1,3,5,7,8-pentaene, an Isonaphthalene: Generation and Trapping Reactions}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58639}, year = {1992}, abstract = {No abstract available}, subject = {Organische Chemie}, language = {en} } @article{HegmannDitterichHuettneretal.1992, author = {Hegmann, J. and Ditterich, E. and H{\"u}ttner, G. and Christl, Manfred and Peters, K. and Peters, E.-M. and Schnering, H. G. von}, title = {δ-Chlor-δ-lactone aus γ-Oxoketenen}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58649}, year = {1992}, abstract = {No abstract available}, subject = {Organische Chemie}, language = {de} } @article{ChristlMueller1993, author = {Christl, Manfred and M{\"u}ller, H.}, title = {Induktiver Effekt, negative Hyperkonjugation und Gegenion sind nicht die Ursache der besonderen Eigenschaften des Bicyclo[3.2.1]octa-3,6-dien-2-yl-Anions. - Eine NMR-Studie mit phenylsubstituierten Modellen}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58655}, year = {1993}, abstract = {No abstract available}, subject = {Organische Chemie}, language = {de} } @article{HerbertChristl1979, author = {Herbert, R. and Christl, Manfred}, title = {Bicyclo[2.1.1]hexane aus Tricyclo[3.1.0.0\(^{2,6}\)]hexanen}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58042}, year = {1979}, abstract = {No abstract available}, subject = {Organische Chemie}, language = {de} } @article{ChristlHerbert1979, author = {Christl, Manfred and Herbert, R.}, title = {Der Einfluß anellierter Ringe auf die \(^{13}\)C-NMR-chemischen Verschiebungen von Tricyclo[3.1.0.0\(^{2,6}\)]hexan- und Bicyclo[2.1.1]hexan-Derivaten}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58058}, year = {1979}, abstract = {No abstract available}, subject = {Organische Chemie}, language = {de} } @article{ChristlLangHerbertetal.1980, author = {Christl, Manfred and Lang, R. and Herbert, R. and Freitag, G.}, title = {Zusammenhang zwischen Orbitalcharakter und Reaktionsprodukt bei der Umsetzung von Benzvalen und Homobenzvalen mit Thiophenol}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58065}, year = {1980}, abstract = {No abstract available}, subject = {Organische Chemie}, language = {de} } @article{ChristlLangLechner1980, author = {Christl, Manfred and Lang, R. and Lechner, M.}, title = {Tetra- und pentacyclische Tricyclo[4.1.0.0\(^{2,7}\)]hept-3-en-Derivate; Abfangprodukte des Tricyclo[4.1.0.0\(^{2,7}\)]hepta-3,4-diens}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58078}, year = {1980}, abstract = {No abstract available}, subject = {Organische Chemie}, language = {de} } @article{ChristlReuchlein1990, author = {Christl, Manfred and Reuchlein, H.}, title = {Synthesen und NMR-Spektren von 2,3-Dihydro-1,3-methanoindenderivaten und 1,2,3,5-Tetrahydro-1,3-methanopentalen}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58549}, year = {1990}, abstract = {No abstract available}, subject = {Organische Chemie}, language = {de} } @article{ChristlHerzogKemmer1986, author = {Christl, Manfred and Herzog, C. and Kemmer, P.}, title = {Tricyclo[5.1.0.0\(^{2,8}\)]oct-3-en, -oct-4-en und -octan: Darstellung und Thermolyse der Hydroderivate des Octavalens}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58310}, year = {1986}, abstract = {No abstract available}, subject = {Organische Chemie}, language = {de} } @article{ChristlHerzogNusser1986, author = {Christl, Manfred and Herzog, C. and Nusser, R.}, title = {Bicyclo[4.1.1]octa-2,4-dien, -oct-2-en, -oct-3-en und -octan aus Norpinen}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58326}, year = {1986}, abstract = {No abstract available}, subject = {Organische Chemie}, language = {de} } @article{ChristlHerzog1986, author = {Christl, Manfred and Herzog, C.}, title = {\(^{13}\)C-NMR-Spektroskopie: Besondere Hochfeldeffekte in Bicyclo[4.1.1]- und Tricyclo[5.1.0.0\(^{2,8}\)]octan-Systemen (1,3-Cycloheptadien-Effekt) und besondere Tieffeldeffekte in Dihalogenbicyclo[2.1.1]hex-2-enen (Cyclopenten-Effekt)}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58334}, year = {1986}, abstract = {No abstract available}, subject = {Organische Chemie}, language = {de} } @article{ChristlHerzog1987, author = {Christl, Manfred and Herzog, C.}, title = {3-(Phenylsulfonyl)tricyclo[4.1.0.0\(^{2,7}\)]hept-4-en-3-yllithium}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58340}, year = {1987}, abstract = {Phenyl(tricyclo[4.1.0.0\^(^{2,7}\)] hept-4-en-3-yl)sulfone 8 has been prepared in two steps from 4,S-dlbromohomobenzvalene (6) and deprotonated to give the title compound 9. The carbon-13 NMR spectrum of 9 reveals a considerable interaction between the allyl anion moiety and the bicyclobutane system.}, subject = {Organische Chemie}, language = {de} } @article{ChristlSchreck1987, author = {Christl, Manfred and Schreck, M.}, title = {7-Arylbicyclo[4.2.0]oct-1-ene - Synthese durch [2+2]-Cycloadditionen von 1,2-Cyclohexadien sowie 1-Methyl-1,2-cyclohexadien und thermische {\"A}quilibrierung der exo/endo-Isomeren}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58352}, year = {1987}, abstract = {Das exo/endo--lsomerenverh{\"a}ltnis Ja: Jb bei der bekannten [2 + 2]-Cycloaddition von Styrol an 1,2-Cyclohexadien (2) wurde als tempcraturabhingiaaefunden. Der Einsatz von (Z)-Dcutcriostyrollicfene den Beweis der Zweistufiakeit dieser Reaktion, und das Diradikal 4 wird als wahrscheinlichste Zwischenstufe anaesehen. Erhitzen von Jb auf 140-170°C f{\"u}hrte zur Binstellung des thermodynamischen Gleichgewichts mit Ja (Ja:3b = 93:7), wobei wieder das Diradikal4 als Zwischenstufe fungieren d{\"u}rfte. Mit Hilfe kinetischer Messungen ermittelte man die Aktivierungsparameter f{\"u}r das System Ja~ 3b. - Aus 2 und den Abfangreagenzien p-Methoxystyrol, 1,1-Diphenylethylen sowie 1-Phenylpropen gingen mit bescheidenen Ausbeuten die Titelverbindungen 6a, b, 7 bzw. 8 hervor. Analoa zu 2 wurde sein l-Methylderivat 13 aus 6,6-Dibrom-1-methylbicyclo[3.1.0]hexan (9) durch Methyllithium freigesetzt. In Gegenwart von Styrol entstand neben den Abfanaprodukten 14a, b auch das Dimere 12 von lJ. - Die 1H-NMR-Spektren der Titelverbindungen belegen eine starre Halbsesselkonformation des Cyclohexentcils mit {\"a}quatorial anellienem Cyclobutanring.}, subject = {Organische Chemie}, language = {de} } @article{KorthMuellerSustmannetal.1987, author = {Korth, H.-G. and M{\"u}ller, W. and Sustmann, R. and Christl, Manfred}, title = {Rearrangement of Free Radicals, XII. ESR Spectroscopic Study of the Ring Opening of the Homobenzvalenyl Radical}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58376}, year = {1987}, abstract = {Abstraction of an allylic hydrogen atom in homobenzvalene (4) either in solurion by photolyticaßy generated tert-butoxyl radicals or in an adamantane matrix by X-rays produces the homobcnzvalenyl radical (5). which tbennally rearranps · to tbe tropylium ndical (1). In solution tbe activation cnergy for the rate determined step of the reaction sequence was detennined· to be 13.4 ± O.S kcal/mol.}, subject = {Organische Chemie}, language = {en} } @article{HegmannChristlPetersetal.1987, author = {Hegmann, J. and Christl, Manfred and Peters, K. and Peters, E.-M. and Schnering, H. G. von}, title = {Intramolekulare [2+2]-Cycloadditionen von γ-Oxoketenen}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58384}, year = {1987}, abstract = {The 1-oxoketenes, which are accessible from methyl 1,3,4-oxadiazin-6-one-2-carboxyIate 1 and cycloalkenes, are shown to undergo an intramolecular [2+2] cycloaddition either on heating or on photolysis to give different sterecisemers of ß-lactones of the 3-oxo-2-oxabicyclo[ 2.2.0]hexane-type.}, subject = {Organische Chemie}, language = {de} } @article{ChristlHegmannReuchleinetal.1987, author = {Christl, Manfred and Hegmann, J. and Reuchlein, H. and Peters, K. and Peters, E.-M. and Schnering, H. G. von}, title = {{\"U}berbr{\"u}ckte neungliedrige α,β-unges{\"a}ttigte Enollactone - Synthese aus 5-Phenyl-1,3,4-oxadiazin-6-on-2-carbons{\"a}ure-methylester und Konfigurationsanalyse}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58395}, year = {1987}, abstract = {The γ-oxoketenes, which are formed from oxadiazinone Ja and strained cyclopentene der1vat1ves, are shown to undergo a pericyclic ring enlargement to give the title compounds 2a, 2b, and 5. In the case of 5, two configurations, one having a cis and the other a trans Iactone functionality, are in equilibrium.}, subject = {Organische Chemie}, language = {de} } @article{ChristlNusserHerzog1988, author = {Christl, Manfred and Nusser, R. and Herzog, C.}, title = {4-Bromoctavalen und zwei (Brommethylen)homobenzvalene anstelle eines erwarteten Bromoctabisvalens}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58409}, year = {1988}, abstract = {No abstract available.}, subject = {Organische Chemie}, language = {de} } @article{ChristlLeiningerMattauch1983, author = {Christl, Manfred and Leininger, Hartmut and Mattauch, Brigitte}, title = {The 13C NMR Spectra of Some Tricyclo[2.2.0.02,6]hexane Derivatives : Unexpected High Field Absorptions Due to Additive gamma-anti Subsituent Effects}, isbn = {x}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-41620}, year = {1983}, abstract = {By means of the BC NMR spectra of tricyclo{2.2.0~rfJ6Jhexane and thirteen of its derivatives the effects of substituents in endo-3- and endo-5-positions on the HC chemical shifts have been determined. The y-anti effects are at least as Jarge as in monosubstituted cyc1obutanes, where the shielding values of second-row hetero substituents exceed those in unstrained systems by far, and higher-row and carbon substituents still cause substantial upfield shifts. In the title system the y-anti effect of a substituent in the endo-3- and endo-5-position are operative additively, and thus shift the absorption of C-J upfieJd by a maximum of 27 ppm with respect to the unsubstituted hydrocarbon.}, language = {en} } @article{IrngartingerReimannLangetal.1990, author = {Irngartinger, H. and Reimann, W. and Lang, R. and Christl, Manfred}, title = {Electron Density Distribution in a Bicyclo[l.l.0]butane}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-31576}, year = {1990}, abstract = {No abstract available}, language = {en} } @article{GigstadRicciJRMarkgrafetal.1991, author = {Gigstad, Kenneth M. and Ricci JR., John S. and Markgraf, J. Hodge and Christl, Manfred and Kraft, Arno}, title = {Strained Heterocyclic Systems : 18. Structure of 1,2,3-Methylidyne-2,3-dihydro-1H-cyclopenta[b]quinoxaline}, isbn = {0108-2701}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-41645}, year = {1991}, abstract = {No abstract available}, language = {en} } @article{ChristlLessMueller1994, author = {Christl, Manfred and Leß, Roland and M{\"u}ller, Heinrich}, title = {6,7-Dimethylene-2,4-diphenylbicyclo[3.2.l]oct-3-en-2-yl Anion : A Test for the Origin of the Unusual Properties of the Bicyclo[3.2.l]octa-3,6-dien-2-yl Anion}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-31547}, year = {1994}, abstract = {No abstract available}, language = {en} } @article{ChristlLanzendoerferFreund1981, author = {Christl, Manfred and Lanzend{\"o}rfer, Ulrike and Freund, Silke}, title = {Olefinadditionen an 2,5-Diphenyl-1,3,4-oxadiazin-6-on}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-41525}, year = {1981}, abstract = {No abstract available}, language = {de} } @article{ChristlLechner1975, author = {Christl, Manfred and Lechner, M.}, title = {Zur intramolekularen Wechselwirkung von Cyclopropylidenen mit dem Bicyclo[1.1.0]butansystem}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-41509}, year = {1975}, abstract = {No abstract available}, language = {de} } @misc{ChristlBruentrup1974, author = {Christl, Manfred and Br{\"u}ntrup, Gisela}, title = {Neue Isomere des Cycloheptatriens: Tricyclo[4.1.0.0^(2,7)]hept-3-en und Tetracyclo[4.1.0.0^(2,4).0^(3,5)]heptan}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-41488}, year = {1974}, abstract = {No abstract available}, language = {de} } @techreport{Christl1986, author = {Christl, Manfred}, title = {Cycloadditions of 1,3,4-Oxadiazin-6-ones}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-41677}, year = {1986}, abstract = {No abstract available}, language = {en} } @article{ChristlRoberts1972, author = {Christl, Manfred and Roberts, John D.}, title = {Carbon-13 Nuclear Magnetic Resonance Spectroscopy : Conformational Analysis of Methyl-Substituted Cycloheptanes, Cycloheptanols, and Cycloheptanones}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-41663}, year = {1972}, abstract = {The 130 chemical shifts were determined of the carbons in 12 cycloheptanes, 21 cycloheptanols, and 8 cycloheptanones. In some cyc1oheptanols and cyc1oheptanones, the assignments have been obtained unambiguously by the synthesis of deuterated derivatives and the use of paramagnetic-shift reagents. Substituent effects for the different types of groups have been calculated. The most informative data about the cyc10heptane conformations were provided by the relatively well understood I' effects. The results are generally in,good agreement with predictions based on the twist-chair form, which has been predicted by Hendrickson to be the most stable conformation. Pairs of cis-trans isomers are found to have rather characteristic differences in their 130 spectra. This fact was used to assign the resonances found for cis-trans mixtures of methyl-substituted cyc1oheptanols to specific isomers.}, language = {en} } @article{ChristlKrimmKraft1990, author = {Christl, Manfred and Krimm, Stefan and Kraft, Arno}, title = {Some Valenes of Benzannelated Five-Membered Heteroarenes - Synthesis and NMR Spectra}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-30026}, year = {1990}, abstract = {No abstract available}, language = {en} } @article{BruentrupChristl1973, author = {Br{\"u}ntrup, Gisela and Christl, Manfred}, title = {Darstellung und Thermolyse der Hexamethyldewarbenzol-Cycloaddukte aromatischer Nitriloxide und des Diphenylnitrilimins}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-30257}, year = {1973}, abstract = {No abstract available}, language = {en} } @article{LanzendoerferChristl1983, author = {Lanzend{\"o}rfer, Franz and Christl, Manfred}, title = {3,4-Bismethylentricyclo[3.1.0.02,6]hexan - Synthese und Diels-Alder-Addition an Tetracyanethylen}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-30263}, year = {1983}, abstract = {No abstract available}, language = {en} } @article{HegmannChristlPetersetal.1988, author = {Hegmann, Joachim and Christl, Manfred and Peters, Karl and Peters, Eva-Maria and Schnering, Hans Georg}, title = {Conjugated and Nonconjugated Cyclopentenones by a Reaction Cascade from Methyl 6-0xo-5-phenyl-1,3,4-oxadiazine-2-carboxylate and 1,3-Butadienes}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-30207}, year = {1988}, abstract = {No abstract available}, language = {en} } @article{HuisgenChristl1967, author = {Huisgen, R. and Christl, Manfred}, title = {1,3-Dipolare Cycloadditionen der Knalls{\"a}ure}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-30227}, year = {1967}, abstract = {No abstract available}, language = {de} } @article{ChristlBraunMueller1992, author = {Christl, Manfred and Braun, Martin and M{\"u}ller, Germar}, title = {1,2,4-Cyclohexatrien, ein Isobenzol, und Bicyclo[4.4.0]deca-1,3,5,7,8-pentaen, ein Isonaphthalin : Erzeugung und Abfangreaktionen}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-30249}, year = {1992}, abstract = {No abstract available}, language = {de} } @article{ChristlLeiningerBrueckner1983, author = {Christl, Manfred and Leininger, Hartmut and Br{\"u}ckner, Dieter}, title = {On the Nature of the Bicyclo [3.2.1]octa-3,6-dien-2-yl Anion: A 13C NMR spectroscopic study}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-30060}, year = {1983}, abstract = {No abstract available}, language = {en} } @article{ChristlLeiningerBrunn1982, author = {Christl, Manfred and Leininger, Hartmut and Brunn, Erich}, title = {Carbon-13 Nuclear Magnetic Resonance Spectra of 7-Heterotetracyclo[4.1.0.02,4.03,5]heptanes. Annelation Effects of Aziridine, Oxirane, and Thiirane Rings. Unusual gamma and delta Substituent Effects}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-30010}, year = {1982}, abstract = {No abstract available}, language = {de} } @article{ChristlLeininger1979, author = {Christl, Manfred and Leininger, Hartmut}, title = {7-Azatetracyclo[4.1.0.02,4.03,5]heptan - ein neues Valenzisomeres des Azepins}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-30034}, year = {1979}, abstract = {No abstract available}, language = {de} } @article{ChristlBuchner1978, author = {Christl, Manfred and Buchner, Wolfgang}, title = {13C-NMR-Spektren von Tetracyclo[4.1.0.02,4.03,5]heptanen, Tetracyclo[5.1.0.02,4.03,5]octanen und Tricyclo[4.1.0.02,7]hept-3-enen. Ungew{\"o}hnliche beta- und gamma-Substituenteneffekte}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-30087}, year = {1978}, abstract = {No abstract available}, language = {de} } @article{Christl1975, author = {Christl, Manfred}, title = {Carbon-13 Chemical Shifts and 13C-15N Coupling Constants of 3,4-Dihydroisoquinoline-15N, its 15N-Oxide and their Conjugate Acids}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-30071}, year = {1975}, abstract = {No abstract available}, language = {en} } @article{ChristlBrunnLanzendorfer1984, author = {Christl, Manfred and Brunn, Erich and Lanzendorfer, Franz}, title = {Reactions of Benzvalene with Tetracyanoethylene, 2,3-Dichloro-5,6-dicyano-rho-benzoquinone, Chlorosulfonyl Isocyanate, and Sulfur Dioxide. Evidence for Concerted 1,4-Cycloadditions to a Vinylcyclopropane System}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-30052}, year = {1984}, abstract = {No abstract available}, language = {en} } @article{Christl1981, author = {Christl, Manfred}, title = {Benzvalen - Eigenschaften und Synthesepotential}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-30041}, year = {1981}, abstract = {No abstract available}, language = {de} } @article{Christl1973, author = {Christl, Manfred}, title = {Cycloaddition an Benzvalen}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-30217}, year = {1973}, abstract = {No abstract available}, language = {de} } @article{ChristlHuisgen1968, author = {Christl, Manfred and Huisgen, R.}, title = {Alte und neue Cycloadditionen der Nitriloxide}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-30237}, year = {1968}, abstract = {No abstract available}, language = {de} } @article{ChristlKrimmKraft1990, author = {Christl, Manfred and Krimm, Stefan and Kraft, Arno}, title = {Einige Valene von benzanellierten f{\"u}nfgliedrigen Heteroarenen - Synthesen und NMR-Spektren}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-31559}, year = {1990}, abstract = {No abstract available}, language = {de} }