@unpublished{ArrowsmithDoemlingSchmidtetal.2019,
  author    = {Arrowsmith, Merle and D{\"o}mling, Michael and Schmidt, Uwe and Werner, Luis and Castro, Abril C. and Jim{\´e}nez-Halla, J. Oscar C. and M{\"u}ssig, Jonas and Prieschl, Dominic and Braunschweig, Holger},
  title     = {Spontaneous trans-Selective Transfer Hydrogenation of Apolar B=B Double Bonds},
  series = {Angewandte Chemie, International Edition},
  journal   = {Angewandte Chemie, International Edition},
  doi       = {10.1002/anie.201902656},
  url       = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-184874},
  year      = {2019},
  abstract  = {The transfer hydrogenation of NHC-supported diborenes with dimethylamine borane proceeds with high selectivity for the trans-1,2-dihydrodiboranes(6). DFT calculations suggest a stepwise proton-first-hydride-second reaction mechanism via an intermediate μ-hydrodiboronium dimethylaminoborate ion pair.},
  language  = {en}
}