@unpublished{WangArrowsmithBraunschweigetal.2017,
  author    = {Wang, Sunewang Rixin and Arrowsmith, Merle and Braunschweig, Holger and Dewhurst, Rian and Paprocki, Valerie and Winner, Lena},
  title     = {CuOTf-mediated intramolecular diborene hydroarylation},
  series = {Chemical Communications},
  journal   = {Chemical Communications},
  doi       = {10.1039/C7CC07371B},
  url       = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-154055},
  year      = {2017},
  abstract  = {Upon complexation to CuOTf, a PMe\(_3\)-stabilized bis(9-anthryl) diborene slowly undergoes an intramolecular hydroarylation reaction at room temperature. Subsequent triflation of the B-H bond with CuOTf, followed by a PMe\(_3\) transfer, finally yields a cyclic sp\(^2\)-sp\(^3\) boryl-substituted boronium triflate salt.},
  language  = {en}
}
@unpublished{MuessigThalerDewhurstetal.2019,
  author    = {Muessig, Jonas H. and Thaler, Melanie and Dewhurst, Rian D. and Paprocki, Valerie and Seufert, Jens and Mattock, James D. and Vargas, Alfredo and Braunschweig, Holger},
  title     = {Phosphine-Stabilized Diiododiborenes: Isolable Diborenes with Six Labile Bonds},
  series = {Angewandte Chemie, International Edition},
  journal   = {Angewandte Chemie, International Edition},
  doi       = {10.1002/anie.201814230},
  url       = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-178608},
  year      = {2019},
  abstract  = {The lability of B=B, B-P and B-halide bonds is combined in the syntheses of the first diiododiborenes. In a series of reactivity tests, these diiododiborenes demonstrate cleavage of all six of their central bonds in different ways, leading to products of B=B hydrogenation and dihalogenation as well as halide exchange.},
  language  = {en}
}
@article{LiuLegareSeufertetal.2020,
  author    = {Liu, Siyuan and L{\´e}gar{\´e}, Marc-Andr{\´e} and Seufert, Jens and Prieschl, Dominic and Rempel, Anna and Englert, Lukas and Dellermann, Theresa and Paprocki, Valerie and Stoy, Andreas and Braunschweig, Holger},
  title     = {2,2′-Bipyridyl as a Redox-Active Borylene Abstraction Agent},
  series = {Inorganic Chemistry},
  volume    = {59},
  journal   = {Inorganic Chemistry},
  number    = {15},
  doi       = {10.1021/acs.inorgchem.0c01383},
  url       = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-215595},
  pages     = {10866-10873},
  year      = {2020},
  abstract  = {2,2′-Bipyridyl is shown to spontaneously abstract a borylene fragment (R-B:) from various hypovalent boron compounds. This process is a redox reaction in which the bipyridine is reduced and becomes a dianionic substituent bound to boron through its two nitrogen atoms. Various transition metal-borylene complexes and diboranes, as a well as a diborene, take part in this reaction. In the latter case, our results show an intriguing example of the homolytic cleavage of a B═B double bond.},
  language  = {en}
}