@article{VolzShinPrinzbachetal.1978, author = {Volz, H. and Shin, J.-H. and Prinzbach, H. and Babsch, H. and Christl, Manfred}, title = {Stability of Tricyclo[4.1.0.0\(^{2,7}\)]heptenyl-Cations}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58001}, year = {1978}, abstract = {No abstract available}, subject = {Organische Chemie}, language = {en} } @article{SchreckChristl1987, author = {Schreck, Michael and Christl, Manfred}, title = {Generation and Interception of 1-Oxa-3,4-cyclohexadiene}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-31601}, year = {1987}, abstract = {No abstract available}, subject = {Chemie}, language = {en} } @article{MarkgrafCortDavisetal.1991, author = {Markgraf, J. H. and Cort, J. R. and Davis, H. A. and Lindeman, N. I. and Myers, C. R. and Kraft, A. and Christl, Manfred}, title = {Strained Heterocyclic Systems. 20. Basicities of Bicyclic Quinoxalines}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58584}, year = {1991}, abstract = {No abstract available}, subject = {Organische Chemie}, language = {en} } @article{LeiningerLanzendoerferChristl1983, author = {Leininger, H. and Lanzend{\"o}rfer, F. and Christl, Manfred}, title = {{\"U}ber die Reduktion des Benzvalenozonids zum cis-1,3-Cyclobutandimethanol mit LiAlH\(_4\)}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58130}, year = {1983}, abstract = {No abstract available}, subject = {Organische Chemie}, language = {en} } @article{LanzendoerferChristl1983, author = {Lanzend{\"o}rfer, Franz and Christl, Manfred}, title = {3,4-Bismethylentricyclo[3.1.0.02,6]hexan - Synthese und Diels-Alder-Addition an Tetracyanethylen}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-30263}, year = {1983}, abstract = {No abstract available}, language = {en} } @article{KorthMuellerSustmannetal.1987, author = {Korth, H.-G. and M{\"u}ller, W. and Sustmann, R. and Christl, Manfred}, title = {Rearrangement of Free Radicals, XII. ESR Spectroscopic Study of the Ring Opening of the Homobenzvalenyl Radical}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58376}, year = {1987}, abstract = {Abstraction of an allylic hydrogen atom in homobenzvalene (4) either in solurion by photolyticaßy generated tert-butoxyl radicals or in an adamantane matrix by X-rays produces the homobcnzvalenyl radical (5). which tbennally rearranps · to tbe tropylium ndical (1). In solution tbe activation cnergy for the rate determined step of the reaction sequence was detennined· to be 13.4 ± O.S kcal/mol.}, subject = {Organische Chemie}, language = {en} } @article{KimChristlKochl1990, author = {Kim, E. and Christl, Manfred and Kochl, J. K.}, title = {Charge-Transfer Cycloaddition of Homobenzvalene with Tetracyanoethylene}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58537}, year = {1990}, abstract = {The transient yellow color observed in the cycloaddition of homobenzvalene (HB) with tetracyanoethylene (TCNE) is associated with the charge-transfer complex [HB, TCNE). The deliberate photoexcitation of [HB,TCNE) affords a mixture of charge-transfer cycloadducts (1, 2, and 3) that differs from that obtained in thermal cycloaddition. The relationship of {HB t TCNE•) radical-ion pair (as the critical reactive intermediate in charge-transfer cycloaddition) to the activation process for thermal cycloaddition is discussed.}, subject = {Organische Chemie}, language = {en} } @article{IrngartingerReimannLangetal.1990, author = {Irngartinger, H. and Reimann, W. and Lang, R. and Christl, Manfred}, title = {Electron Density Distribution in a Bicyclo[l.l.0]butane}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-31576}, year = {1990}, abstract = {No abstract available}, language = {en} } @article{HegmannChristlPetersetal.1988, author = {Hegmann, Joachim and Christl, Manfred and Peters, Karl and Peters, Eva-Maria and Schnering, Hans Georg}, title = {Conjugated and Nonconjugated Cyclopentenones by a Reaction Cascade from Methyl 6-0xo-5-phenyl-1,3,4-oxadiazine-2-carboxylate and 1,3-Butadienes}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-30207}, year = {1988}, abstract = {No abstract available}, language = {en} } @article{GleiterBischofGubernatoretal.1985, author = {Gleiter, Rolf and Bischof, Peter and Gubernator, Klaus and Christl, Manfred and Schwager, Luis and Vogel, Pierre}, title = {2,3-Bis(methylene)bicyclo[2.1.1]hexane and 3,4-Bis(methylene)tricyclo[3.1.0.0\(^{2,6}\)]hexane : Interaction between a π System and a Cyclobutane or Bicyclobutane Moiety}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-31845}, year = {1985}, abstract = {The He (I) photoelectron spectra of 2-bicyclo[2.1.l]hexene (1), 2,3-bis(methylene)bicyclo[2.1.l]hexane (3), and 3,4-bis(methylene)tricyclo[3.l.O.0\(^{2.6}\)]hexane (4) have been investigated. The assignment given is based on a ZDO model and semiempirical calculations. Tagether with the PE data of benzvalene (2), the reported data allow a comparison between 1-2 and 3-4. This yields a measure of the interactions between 8 cyclobutane or 8 bicyclobutane moiety and a double bond system within a ZDO model. The resonance integral found in the case of 1 and 3 amounts to -1.9 eV, that for 2 and 4, to -2.3 eV. The investigations furthermore reveal that the electronic factors which contribute to the higher reactivity of the bicyclobutane compounds amount to 5 kcal/mol.}, subject = {Chemie}, language = {en} }