@article{BentleyChristlKemmeretal.1994,
  author    = {Bentley, T. W. and Christl, Manfred and Kemmer, R. and Llewellyn, G. and Oakley, J. E.},
  title     = {Kinetic and Spectroscopic Characterisation of Highly Reactive Methanesulfonates. Leaving Group Effects for Solvolyses and Comments on Geminal Electronic Effects Influencing S\(_N\)1 Reactivity},
  url       = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58748},
  year      = {1994},
  abstract  = {Highly reactive methanesulfonates (mesylates, ROMs) have been prepared from 1-phenylethanol. cyclohex-2-en-1-ol, diphenylmethanol and p-methoxybenzyl alcohol by treatment with methanesulfonyl chloride and triethylamine in dichloro- or trichloro-methane at - 20 to 0 °C. The mesylates. characterised in solution by \(^1\)H and \(^{13}\)C NMR at -20 °C, were obtained in satisfactory purity (ca. 95\%) in cold solutions but they decomposed by reaction with chloride, triethylamine or the parent alcohol. Rate constants for solvolyses in aqueous acetone and aqueous ethanol have been determined by a fast response conductimetric method. Product selectivities for solvolyses of pmethoxybenzyl mesylate in aqueous ethanol and methanol at 0 °C have been determined by HPLC. From additional new or Iiterature kinetic data for solvolyses of corresponding bromides. chlorides and p-nitrobenzoates (OPNB). Br/CI. OMs/Br and OMs/OPNB rate ratios were calculated; the results are consistent with electronic effects stabilising the carbocationic transition states and increasing OMs/Br rate ratios for these SN 1 solvolyses; none of the evidence supports a geminal electronic effect on Br/CI rate ratios (e.g. caused by stabilisation of the initial state in pmethoxybenzyl chloride). Steric effects on ester /halide rate ratios for solvolyses of tertiary substrates are confirmed. Relative rates over a 10\(^{16}\) range for ester and halide leaving groups are evaluated for solvolyses of 1-phenylethyl substrates in 80\% ethanol-water. updating previous work by Noyce et al. (1972).},
  subject      = {Organische Chemie},
  language  = {en}
}
@article{HerzogLangBrueckneretal.1986,
  author    = {Herzog, C. and Lang, R. and Br{\"u}ckner, D. and Kemmer, P. and Christl, Manfred},
  title     = {Norpinene (Bicyclo[3.1.1]hept-2-ene) aus Homobenzvalenen (Tricyclo[4.1.0.0\(^{2,7}\)]hept-3-enen)},
  url       = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58302},
  year      = {1986},
  abstract  = {No abstract available},
  subject      = {Organische Chemie},
  language  = {de}
}
@article{ChristlGerstnerKemmeretal.1994,
  author    = {Christl, Manfred and Gerstner, E. and Kemmer, R. and Llewellyn, G. and Bentley, T. W.},
  title     = {Elektrophile Additionen an das Bicyclo[1.1.0]butan-System von 1-Phenyl- und 1-(4-Anisyl)tricyclo[4.1.0.0\(^{2,7}\)]heptan: S{\"a}ure-katalysierte Reaktionen mit Wasser und Methanol, Anlagerung von Essigs{\"a}ure und Oxymercurierung},
  url       = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58696},
  year      = {1994},
  abstract  = {No abstract available},
  subject      = {Organische Chemie},
  language  = {de}
}
@article{BentleyNormanGerstneretal.1993,
  author    = {Bentley, T. W. and Norman, S. J. and Gerstner, E. and Kemmer, R. and Christl, Manfred},
  title     = {Solvolysis of Tricyclo[3.1.0.0\(^{2,6}\)]hex-3-yl and Bicyclo[2.1.1]hex-2-yl Sulfonates},
  url       = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58689},
  year      = {1993},
  abstract  = {No abstract available},
  subject      = {Organische Chemie},
  language  = {en}
}
@article{GerstnerKemmerChristl1994,
  author    = {Gerstner, E. and Kemmer, R. and Christl, Manfred},
  title     = {Elektrophile Additionen an das Bicyclo[1.1.0]butan-System von Tricyclo[4.1.0.0\(^{2,7}\)]-heptan-Derivaten: Halogen-Elektrophile},
  url       = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-58700},
  year      = {1994},
  abstract  = {No abstract available},
  subject      = {Organische Chemie},
  language  = {de}
}