TY  - JOUR
A1  - Hock, Andreas
A1  - Werner, Luis
A1  - Riethmann, Melanie
A1  - Radius, Udo
T1  - Bis‐NHC Aluminium and Gallium Dihydride Cations [(NHC)\(_{2}\)EH\(_{2}\)]\(^{+}\) (E = Al, Ga)
JF  - European Journal of Inorganic Chemistry
N2  - The NHC alane and gallane adducts (NHC)·AlH\(_{2}\)I (NHC = Me\(_{2}\)Im\(^{Me}\) 7, iPr\(_{2}\)Im 8, iPr\(_{2}\)Im\(^{Me}\) 9) and (NHC)·GaH\(_{2}\)I (NHC = Me\(_{2}\)Im\(^{Me}\) 10, iPr\(_{2}\)Im\(^{Me}\) 11, Dipp\(_{2}\)Im 12; R\(_{2}\)Im = 1,3‐di‐organyl‐imidazolin‐2‐ylidene; Dipp = 2,6‐diisopropylphenyl; iPr = isopropyl; Me\(_{2}\)Im\(^{Me}\) = 1,3,4,5‐tetra‐methyl‐imidazolin‐2‐ylidene) were prepared either by the simple yet efficient reaction of the NHC adduct (NHC)·AlH\(_{3}\) with elemental iodine or by the treatment of (NHC)·GaH\(_{3}\) with an excess of methyl iodide at room temperature. The reaction of one equivalent of the group 13 NHC complexes with an additional equivalent of the corresponding NHC afforded cationic aluminium and gallium hydrides [(NHC)\(_{2}\)·AlH\(_{2}\)]\(^{+}\)I− (NHC = Me\(_{2}\)Im\(^{Me}\) 13, iPr\(_{2}\)Im 14, iPr\(_{2}\)Im\(^{Me}\) 15) and [(NHC)\(_{2}\)·GaH\(_{2}\)]\(^{+}\)I− (NHC = Me\(_{2}\)Im\(^{Me}\) 16, iPr\(_{2}\)Im\(^{Me}\) 17) and the normal and abnormal NHC coordinated compound [(Dipp\(_{2}\)Im)·GaH\(_{2}\)(aDipp\(_{2}\)Im)]+I− 18. Compounds 7–18 were isolated and characterized by means of elemental analysis, IR and multinuclear NMR spectroscopy and by X‐ray diffraction of the compounds 7, 9, 10, 15, 16 and 18.
KW  - aluminium
KW  - cations
KW  - Gallium
KW  - main group elements
KW  - heterocyclic carbenes
Y1  - 2020
U6  - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:bvb:20-opus-217928
VL  - 2020
IS  - 42
SP  - 4015
EP  - 4023
ER  - 
TY  - THES
A1  - Müssig, Jonas Heinrich
T1  - Synthese und Reaktvität von Gruppe 13 Elementhalogeniden gegenüber metallischen und nicht-metallischen Lewis-Basen
T1  - Synthesis and Reactivity of Group 13 Elemental halides towards Metal and Nonmetal Lewis-Bases
N2  - Im Rahmen der vorliegenden Arbeit wurden Dibortetrahalogenide dargestellt, deren Eigenschaften strukturell sowie spektroskopisch analysiert und deren Reaktivität gegenüber Lewis-basischen Hauptgruppenelementverbindungen untersucht. Durch anschließende Reaktivitätsstudien konnten unter anderem neuartige Diborene dargestellt und analysiert werden.
Weiterhin wurde die Verbindungsklasse der Elementhalogenide der Gruppe 13 in der Oxidationsstufe +2 (B, Ga, In) und +3 (In) bezüglich ihrer Reaktivität gegenüber Übergangsmetall Lewis-Basen untersucht. Die gebildeten, neuartigen Bindungsmodi der Gruppe 13 Elemente am Übergangsmetall wurden strukturell, spektroskopisch sowie quantenchemisch analysiert.
N2  - As a part of the present work diborontetrahalides were synthesized, analyzed and their reactivity was investigated towards Lewis-basic main group compounds. Subsequent reactivity studies were performed and novel Diborenes were synthesized and analyzed.
Furthermore the reactivity of group 13 elemental halides in the oxidation state +2 (B, Ga, In) and +3 (In) was investigated towards Lewis-basic transition metal complexes. The novel bonding motifs of the group 13 elements at the metal center were investigated structurally, spectroscopically and by quantum chemical calculations.
KW  - Übergangsmetallkomplex
KW  - Bor
KW  - Lewis-Base
KW  - Gallium
KW  - Indium
KW  - Gruppe 13 element
KW  - Diboren
Y1  - 2020
U6  - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:bvb:20-opus-179831
ER  -