TY  - JOUR
A1  - Riad, Noura M.
A1  - Zlotos, Darius P.
A1  - Holzgrabe, Ulrike
T1  - Crystal structure of 5,11-dihydropyrido[2,3-b][1,4]benzodiazepin-6-one.
JF  - Acta Crystallographica Section E Crystallographic Communications
N2  - The title compound, C\(_{12}\)H\(_{9}\)N\(_{3}\)O, is an inter­mediate in the synthesis of the muscarinic M2 receptor antagonist AFDX-384. The seven-membered ring adopts a boat conformation and the dihedral angle between the planes of the aromatic rings is 41.51 (9)°. In the crystal, mol­ecules are linked into [001] chains of alternating inversion dimers formed by pairs of N-H・・・O hydrogen bonds and pairs of N-H・・・N hydrogen bonds. In both cases, R\(_{2}\)\(^{2}\)(8) loops are generated.
KW  - crystal structure
KW  - pyridobenzodiazepine
KW  - boat conformation
KW  - hydrogen bonding
Y1  - 2015
U6  - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:bvb:20-opus-149627
VL  - E71
ER  -