TY  - THES
A1  - Schäfer, Marius
T1  - Darstellung und Reaktivität von Iminoboranen sowie deren Einsatz bei der Synthese von Azaborininen
T1  - Synthesis and Reactivity of Iminoboranes and their Usage in the  Synthesis of Azaborinines
N2  - Die Dissertation befasst sich mit der Darstellung von Iminoboranen sowie deren Verwendung bei der Rhodium-vermittelten Synthese von Azaborininen.
N2  - The first examples of adducts of cyclic alkyl(amino) carbenes (cAACs) and N-heterocyclic carbenes (NHCs) with iminoboranes have been synthesized and fully characterized. Furthermore new synthetic route to functionalized 1,2 and 1,4-azaborinines has been developed utilizing a [2+2]/[2+4] cycloaddition reaction of di-tert-butyliminoborane and the unsymmetric (tert-butylimino)mesityborane with a series of alkynes in presence of the rhodium complex [{RhCl(PiPr3)2}]2.
KW  - Iminoborane
KW  - Azaborinine
Y1  - 2016
U6  - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:bvb:20-opus-136959
ER  -