TY  - JOUR
A1  - Liu, Xiaocui
A1  - Ming, Wenbo
A1  - Friedrich, Alexandra
A1  - Kerner, Florian
A1  - Marder, Todd B.
T1  - Copper-Catalyzed Triboration of Terminal Alkynes Using B\(_2\)pin\(_2\): Efficient Synthesis of 1,1,2-Triborylalkenes
JF  - Angewandte Chemie International Edition
N2  - We report herein the catalytic triboration of terminal alkynes with B\(_2\)pin\(_2\) (bis(pinacolato)diboron) using readily available Cu(OAc)\(_2\) and P\(^n\)Bu\(_3\). Various 1,1,2‐triborylalkenes, a class of compounds that have been demonstrated to be potential matrix metalloproteinase (MMP‐2) inhibitors, were obtained directly in moderate to good yields. The process features mild reaction conditions, a broad substrate scope, and good functional group tolerance. This copper‐catalyzed reaction can be conducted on a gram scale to produce the corresponding 1,1,2‐triborylalkenes in modest yields. The utility of these products was demonstrated by further transformations of the C−B bonds to prepare gem ‐dihaloborylalkenes (F, Cl, Br), monohaloborylalkenes (Cl, Br), and trans ‐diaryldiborylalkenes, which serve as important synthons and have previously been challenging to prepare.
KW  - boronate esters
KW  - borylation
KW  - cross-coupling
KW  - diboration
KW  - halogenation
Y1  - 2020
U6  - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:bvb:20-opus-206694
VL  - 59
IS  - 1
ER  - 
TY  - JOUR
A1  - Grüne, Jeannine
A1  - Londi, Giacomo
A1  - Gillett, Alexander J.
A1  - Stähly, Basil
A1  - Lulei, Sebastian
A1  - Kotova, Maria
A1  - Olivier, Yoann
A1  - Dyakonov, Vladimir
A1  - Sperlich, Andreas
T1  - Triplet Excitons and Associated Efficiency‐Limiting Pathways in Organic Solar Cell Blends Based on (Non‐) Halogenated PBDB‐T and Y‐Series
JF  - Advanced Functional Materials
N2  - The great progress in organic photovoltaics (OPV) over the past few years has been largely achieved by the development of non‐fullerene acceptors (NFAs), with power conversion efficiencies now approaching 20%. To further improve device performance, loss mechanisms must be identified and minimized. Triplet states are known to adversely affect device performance, since they can form energetically trapped excitons on low‐lying states that are responsible for non‐radiative losses or even device degradation. Halogenation of OPV materials has long been employed to tailor energy levels and to enhance open circuit voltage. Yet, the influence on recombination to triplet excitons has been largely unexplored. Using the complementary spin‐sensitive methods of photoluminescence detected magnetic resonance and transient electron paramagnetic resonance corroborated by transient absorption and quantum‐chemical calculations, exciton pathways in OPV blends are unravelled employing the polymer donors PBDB‐T, PM6, and PM7 together with NFAs Y6 and Y7. All blends reveal triplet excitons on the NFA populated via non‐geminate hole back transfer and, in blends with halogenated donors, also by spin‐orbit coupling driven intersystem crossing. Identifying these triplet formation pathways in all tested solar cell absorber films highlights the untapped potential for improved charge generation to further increase plateauing OPV efficiencies.
KW  - halogenation
KW  - non‐fullerene acceptors
KW  - organic photovoltaics
KW  - spin physics
KW  - triplet excitons
Y1  - 2023
U6  - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:bvb:20-opus-312164
VL  - 33
IS  - 12
ER  -