TY  - JOUR
A1  - Gessner, Viktoria H.
T1  - Diphenyl[2-(phenyl-sulfon-yl)propan-2-yl]-\(\lambda^5\)-phosphanethione
JF  - Acta crystallographica. Section E, Structure reports online
N2  - The title compound, \(C_{21}H_{21}O_2PS_2\), was obtained from the corresponding dilithio methandiide by treatment with iodo-methane. The bond lengths and angles deviate considerably from those in the dimetallated compound. These differences are most pronounced in the PCS backbone. While the title compound features C-P and C-S distances of 1.9082(17) and 1.8348(17)Å, respectively, the dianion showed \(C-P_{av}\) distances shortened by 11% [1.710(4)Å] and C-S distances shortened by 12% [1.614(3)Å]. Additionally, the P-C-S angle experiences a contraction by methyl-ation of the dianion from 121.4(2) to 111.96(9)° in the title compound.
KW  - wR factor = 0.068
KW  - mean σ(C–C) = 0.003 Å
KW  - T = 173 K
KW  - single-crystal X-ray study
KW  - R factor = 0.025
KW  - data-to-parameter ratio = 14.6
Y1  - 2012
U6  - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:bvb:20-opus-123635
VL  - E68
IS  - o1045
ER  - 
TY  - JOUR
A1  - Finze, Maik
A1  - Reiss, Guido J.
A1  - Frohn, Hermann-Josef
T1  - 2,3,5,6-Tetrafluoro-1,4-bis(trimethylsilyl)benzene
N2  - no abstract available
KW  - Chemie
KW  - single-crystal X-ray study
KW  - T = 199 K
KW  - R factor = 0.027
KW  - wR factor = 0.068
KW  - data-to-parameter ratio = 14.0.
Y1  - 2012
U6  - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:bvb:20-opus-75401
ER  -