TY  - JOUR
A1  - Philipp, Michael S. M.
A1  - Radius, Udo
T1  - A Versatile Route To Cyclic (Alkyl)(Amino)Carbene–Stabilized Stibinidenes
JF  - Zeitschrift für Anorganische und Allgemeine Chemie
N2  - A convenient route for the synthesis of the cAAC\(^{Me}\) (cAAC=cyclic (alkyl)(amino)carbene, cAAC\(^{Me}\)=1-(2,6-di-iso-propylphenyl)-3,3,5,5-tetramethyl-pyrrolidin-2-ylidene) and cAAC\(^{Cy}\) (cAAC\(^{Cy}\)=2-azaspiro[4.5]dec-2-(2,6-diisopropylphenyl)-3,3-dimethyl-1-ylidene) stabilized stibinidenes cAAC\(^{Me}\)⋅SbMes (2a) (Mes=2,4,6-trimethylphenyl) and cAAC\(^{Cy}\)⋅SbMes (2b) is reported. A mechanism for the formation of [cAAC\(^{R}\)Cl][SbCl\(_{3}\)Mes] 1 and cAAC\(^{R}\)⋅SbMes 2 from the reaction of cAAC with the antimony(III) precursor SbCl\(_{2}\)Mes, which proceeds via the isolable intermediate [cAAC\(^{R}\)SbClMes][SbCl\(_{3}\)Mes] (3), is proposed.
KW  - stibinidenes
KW  - antimony
KW  - cyclic (alkyl)(amino)carbenes
KW  - lewis acid/base adducts
KW  - main group element halides
Y1  - 2022
U6  - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:bvb:20-opus-318272
SN  - 0044-2313
VL  - 648
IS  - 17
ER  -