TY  - JOUR
A1  - Schlosser, Julika
A1  - Cibulka, Radek
A1  - Groß, Philipp
A1  - Ihmels, Heiko
A1  - Mohrschladt, Christian J.
T1  - Visible‐Light‐Induced Di‐\(\pi\)‐Methane Rearrangement of Dibenzobarrelene Derivatives
JF  - ChemPhotoChem
N2  - It is demonstrated that the di‐\(\pi\)‐methane (DPM) rearrangement of carbonyl‐substituted dibenzobarrelene (9,10‐dihydro‐9,10‐ethenoanthracene) derivatives is induced by visible‐light‐induced triplet photosensitization with Ir(ppy)\(_{3}\), Ir(dFppy)\(_{3}\) or 1‐butyl‐7,8‐dimethoxy‐3‐methylalloxazine as catalysts, whereas derivatives that lack carbonyl substituents are photoinert under these conditions. Notably, the products are formed almost quantitatively.
KW  - dibenzosemibullvalenes
KW  - di-\(\pi\)-methane rearrangement
KW  - ethenoanthracenes
KW  - photocatalysis
KW  - photosensitization
Y1  - 2020
U6  - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:bvb:20-opus-212633
VL  - 4
IS  - 2
SP  - 132
EP  - 137
ER  - 
TY  - THES
A1  - Mohrschladt, Christian J.
T1  - Synthese und Untersuchung der photochemischen und photophysikalischen Eigenschaften Donor-Akzeptor-substituierter Anthracenderivate
T1  - Synthesis and Analysis of the Photochemical and Photophysical Properties of Donor-acceptor-substituted Anthracene Derivatives
N2  - In der vorliegenden Arbeit wurde gezeigt, dass Donor-Akzeptor-substituierte Anthracen- und Ethenoanthracenderivate bemerkenswerte photophysikalische und photochemische Eigenschaften aufweisen. So bieten derartige Anthracenderivate eine interessante Grundlage sowohl zur Entwicklung von Fluoreszenzsonden beispielsweise für Schwermetallionen wie auch zur Entwicklung von molekularen Schaltern für die Datenverarbeitung. Weiterhin stellen die untersuchten Anthracene und Ethenoanthracene hervorragende Systeme zur systematischen Untersuchung von Substituenteneinflüssen auf Photoreaktionen dar.
N2  - It has been demonstrated that donor-acceptor-substituted anthracene and ethenoanthracene derivatives exhibit remarkable photophysical and photochemical properties. Such anthracene derivatives serve as an useful basis for the development of fluorescence sensor e.g. for metall ions as well as molecular switches for data processing. Moreover, the anthracenes and ethenoanthracenes present excellent systems for systematic investigation of substituent effects on photoreactions.
KW  - Anthracenderivate
KW  - Photochemie
KW  - Photophysik
KW  - Anthracenderivate
KW  - Synthese
KW  - Fluoreszenzschalter
KW  - Dibenzobarrelene
KW  - Photochemie
KW  - Anthracene derivatives
KW  - synthesis
KW  - fluorescence switches
KW  - dibenzobarrelenes
KW  - photochemistry
Y1  - 2003
U6  - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:bvb:20-opus-8486
ER  -