TY  - INPR
A1  - Stoy, Andreas
A1  - Böhnke, Julian
A1  - Jiménez-Halla, J. Oscar C.
A1  - Dewhurst, Rian D.
A1  - Thiess, Torsten
A1  - Braunschweig, Holger
T1  - CO\(_2\) Binding and Splitting by Boron–Boron Multiple Bonds
T2  - Angewandte Chemie, International Edition
N2  - CO\(_2\) is found to undergo room-temperature, ambient- pressure reactions with two species containing boron-boron multiple bonds, leading to incorporation of either one or two CO\(_2\) molecules. In one case, a thermally-unstable intermediate was structurally characterized, indicating the operation of an initial 2+2 cycloaddition mechanism in the reaction.
KW  - carbon dioxide
KW  - CO2 fixation
KW  - diborenes
KW  - diborynes
KW  - boron
Y1  - 2018
U6  - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:bvb:20-opus-164265
N1  - This is the pre-peer reviewed version of the following article: A. Stoy, J. Böhnke, J. O. C. Jiménez‐Halla, R. D. Dewhurst, T. Thiess, H. Braunschweig, Angew. Chem. Int.Ed. 2018, 57,5947 –5951, which has been published in final form at DOI: 10.1002/anie.201802117. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.
ER  - 
TY  - JOUR
A1  - Brunecker, Carina
A1  - Müssig, Jonas H.
A1  - Arrowsmith, Merle
A1  - Fantuzzi, Felipe
A1  - Stoy, Andreas
A1  - Böhnke, Julian
A1  - Hofmann, Alexander
A1  - Bertermann, Rüdiger
A1  - Engels, Bernd
A1  - Braunschweig, Holger
T1  - Boranediyl‐ and Diborane(4)‐1,2‐diyl‐Bridged Platinum A‐Frame Complexes
JF  - Chemistry – A European Journal
N2  - Diplatinum A‐frame complexes with a bridging (di)boron unit in the apex position were synthesized in a single step by the double oxidative addition of dihalo(di)borane precursors at a bis(diphosphine)‐bridged Pt\(^{0}\)\(_{2}\) complex. While structurally analogous to well‐known μ‐borylene complexes, in which delocalized dative three‐center‐two‐electron M‐B‐M bonding prevails, theoretical investigations into the nature of Pt−B bonding in these A‐frame complexes show them to be rare dimetalla(di)boranes displaying two electron‐sharing Pt−B σ‐bonds. This is experimentally reflected in the low kinetic stability of these compounds, which are prone to loss of the (di)boron bridgehead unit.
KW  - boron
KW  - bonding
KW  - EDA-NOCV
KW  - oxidative addition
KW  - platinum
Y1  - 2020
U6  - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:bvb:20-opus-214707
VL  - 26
IS  - 39
SP  - 8518
EP  - 8523
ER  -