Bis(μ-diisopropyl-phosphanido-\(κ^2\)P:P)bis-[hydrido(triisopropyl-phosphane-κP)platinum(II)]
Please always quote using this URN: urn:nbn:de:bvb:20-opus-123723
- In the centrosymmetric molecular structure of the title compound \([Pt_2(C_6H_{14}P)_2H_2)(C_9H_{21}P)_2]\), each \(Pt^{II}\) atom is bound on one side to a phosphane ligand \((PiPr_3)\) and a hydrido ligand. On the other side, it is bound to two phosphanide ligands \((μ-PiPr_2)\), which engage a bridging position between the two \(Pt^{II}\) atoms, forming a distorted square-planar structure motif. The PtPt distance is 3.6755(2)Å. A comparable molecular structure was observed forIn the centrosymmetric molecular structure of the title compound \([Pt_2(C_6H_{14}P)_2H_2)(C_9H_{21}P)_2]\), each \(Pt^{II}\) atom is bound on one side to a phosphane ligand \((PiPr_3)\) and a hydrido ligand. On the other side, it is bound to two phosphanide ligands \((μ-PiPr_2)\), which engage a bridging position between the two \(Pt^{II}\) atoms, forming a distorted square-planar structure motif. The PtPt distance is 3.6755(2)Å. A comparable molecular structure was observed for bis-(μ-di-tert-butyl-phosphanido)bis-[hydrido(triethyl-phosphane)platinum(II)] [Itazaki et al. (2004 ). Organometallics, 23, 1610-1621].…
| Author: | Nicole Arnold, Holger BraunschweigORCiD, Alexander Damme |
|---|---|
| URN: | urn:nbn:de:bvb:20-opus-123723 |
| Document Type: | Journal article |
| Faculties: | Fakultät für Chemie und Pharmazie / Institut für Anorganische Chemie |
| Language: | English |
| Parent Title (English): | Acta crystallographica. Section E, Structure reports online |
| Year of Completion: | 2012 |
| Volume: | E68 |
| Pagenumber: | m808 |
| Source: | Acta Crystallographica (2012). E68, m808 [doi:10.1107/S1600536812022829] |
| DOI: | https://doi.org/http://dx.doi.org/10.1107/S1600536812022829 |
| Pubmed Id: | https://pubmed.ncbi.nlm.nih.gov/PMC3379133 |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 548 Kristallografie |
| Tag: | R factor = 0.018; T = 100 K; data-to-parameter ratio = 22.3; mean σ(C–C) = 0.004 Å; single-crystal X-ray study; wR factor = 0.038 |
| Release Date: | 2015/12/23 |
| Licence (German): |  CC BY: Creative-Commons-Lizenz: Namensnennung |