Spontaneous trans‐Selective Transfer Hydrogenation of Apolar B=B Double Bonds

Please always quote using this URN: urn:nbn:de:bvb:20-opus-184874
  • The transfer hydrogenation of NHC-supported diborenes with dimethylamine borane proceeds with high selectivity for the trans-1,2-dihydrodiboranes(6). DFT calculations suggest a stepwise proton-first-hydride-second reaction mechanism via an intermediate μ-hydrodiboronium dimethylaminoborate ion pair.
Metadaten
Author: Merle Arrowsmith, Michael Dömling, Uwe Schmidt, Luis Werner, Abril C. Castro, J. Oscar C. Jiménez-Halla, Jonas Müssig, Dominic Prieschl, Holger Braunschweig
URN:urn:nbn:de:bvb:20-opus-184874
Document Type:Preprint
Faculties:Fakultät für Chemie und Pharmazie / Institut für Anorganische Chemie
Language:English
Parent Title (English):Angewandte Chemie, International Edition
Year of Completion:2019
Source:M. Dömling, M. Arrowsmith, U. Schmidt, L. Werner, A. C. Castro, J. O. C. Jiménez-Halla, R. Bertermann, J. Müssig, D. Prieschl, H. Braunschweig, Angew. Chem. Int. Ed. 2019, 58, 9782. doi:10.1002/anie.201902656
DOI:https://doi.org/10.1002/anie.201902656
Dewey Decimal Classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 546 Anorganische Chemie
Tag:DFT mechanism; amine borane dehydrocoupling; diboranes; diborene; transfer hydrogenation
Release Date:2019/07/30
Note:
This is the pre-peer reviewed version of the following article: M. Dömling, M. Arrowsmith, U. Schmidt, L. Werner, A. C. Castro, J. O. C. Jiménez-Halla, R. Bertermann, J. Müssig, D. Prieschl, H. Braunschweig, Angew. Chem. Int. Ed. 2019, 58, 9782. doi:10.1002/anie.201902656, which has been published in final form at  https://doi.org/10.1002/anie.201902656. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
EU-Project number / Contract (GA) number:669054
OpenAIRE:OpenAIRE
Licence (German):License LogoDeutsches Urheberrecht