Formation of a stable radical by oxidation of a tetraorganoborate
Please always quote using this URN: urn:nbn:de:bvb:20-opus-191321
- Herein, we describe the selective formation of a stable neutral spiroborate radical by one-electron oxidation of the corresponding tetraorganoborate salt Li[B(C\(_4\)Ph\(_4\))\(_2\)], formally containing a tetrahedral borate centre and a s-cis-butadiene radical cation as the spin-bearing site. Spectroscopic and computational methods have been used to determine the spin distribution and the chromism observed in the solid state.
Author: | Holger Braunschweig, Ivo Krummenacher, Lisa Mailänder, Leanne Pentecost, Alfredo Vargas |
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URN: | urn:nbn:de:bvb:20-opus-191321 |
Document Type: | Journal article |
Faculties: | Fakultät für Chemie und Pharmazie / Institut für Anorganische Chemie |
Language: | English |
Parent Title (English): | Chemical Communications |
Year of Completion: | 2016 |
Volume: | 52 |
Issue: | 43 |
Pagenumber: | 7005-7008 |
Source: | Chemical Communications (2016) 52:43, S. 7005-7008. https://doi.org/10.1039/c6cc02916g |
DOI: | https://doi.org/10.1039/c6cc02916g |
Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 542 Techniken, Ausstattung, Materialien |
Tag: | chromism; one-electron oxidation; spin distribution; spiroborates; tetraorganoborate salt |
Release Date: | 2021/02/26 |
Licence (German): | ![]() |