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Spontaneous trans‐Selective Transfer Hydrogenation of Apolar B=B Double Bonds
Please always quote using this URN: urn:nbn:de:bvb:20-opus-184874
- The transfer hydrogenation of NHC-supported diborenes with dimethylamine borane proceeds with high selectivity for the trans-1,2-dihydrodiboranes(6). DFT calculations suggest a stepwise proton-first-hydride-second reaction mechanism via an intermediate μ-hydrodiboronium dimethylaminoborate ion pair.
Author: | Merle Arrowsmith, Michael Dömling, Uwe Schmidt, Luis Werner, Abril C. Castro, J. Oscar C. Jiménez-Halla, Jonas Müssig, Dominic Prieschl, Holger BraunschweigORCiD |
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URN: | urn:nbn:de:bvb:20-opus-184874 |
Document Type: | Preprint |
Faculties: | Fakultät für Chemie und Pharmazie / Institut für Anorganische Chemie |
Language: | English |
Parent Title (English): | Angewandte Chemie, International Edition |
Year of Completion: | 2019 |
Source: | M. Dömling, M. Arrowsmith, U. Schmidt, L. Werner, A. C. Castro, J. O. C. Jiménez-Halla, R. Bertermann, J. Müssig, D. Prieschl, H. Braunschweig, Angew. Chem. Int. Ed. 2019, 58, 9782. doi:10.1002/anie.201902656 |
DOI: | https://doi.org/10.1002/anie.201902656 |
Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 546 Anorganische Chemie |
Tag: | DFT mechanism; amine borane dehydrocoupling; diboranes; diborene; transfer hydrogenation |
Release Date: | 2019/07/30 |
EU-Project number / Contract (GA) number: | 669054 |
OpenAIRE: | OpenAIRE |
Note: | This is the pre-peer reviewed version of the following article: M. Dömling, M. Arrowsmith, U. Schmidt, L. Werner, A. C. Castro, J. O. C. Jiménez-Halla, R. Bertermann, J. Müssig, D. Prieschl, H. Braunschweig, Angew. Chem. Int. Ed. 2019, 58, 9782. doi:10.1002/anie.201902656, which has been published in final form at https://doi.org/10.1002/anie.201902656. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. |
Licence (German): | Deutsches Urheberrecht |