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Supramolecular frameworks based on [60]fullerene hexakisadducts
Please always quote using this URN: urn:nbn:de:bvb:20-opus-171996
- [60]Fullerene hexakisadducts possessing 12 carboxylic acid side chains form crystalline hydrogen-bonding frameworks in the solid state. Depending on the length of the linker between the reactive sites and the malonate units, the distance of the [60]fullerene nodes and thereby the spacing of the frameworks can be controlled and for the most elongated derivative, continuous channels are obtained within the structure. Stability, structural integrity and porosity of the material were investigated by powder X-ray diffraction, thermogravimetry and[60]Fullerene hexakisadducts possessing 12 carboxylic acid side chains form crystalline hydrogen-bonding frameworks in the solid state. Depending on the length of the linker between the reactive sites and the malonate units, the distance of the [60]fullerene nodes and thereby the spacing of the frameworks can be controlled and for the most elongated derivative, continuous channels are obtained within the structure. Stability, structural integrity and porosity of the material were investigated by powder X-ray diffraction, thermogravimetry and sorption measurements.…
Author: | Andreas Kraft, Johannes Stangl, Ana-Maria Krause, Klaus Müller-Buschbaum, Florian Beuerle |
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URN: | urn:nbn:de:bvb:20-opus-171996 |
Document Type: | Journal article |
Faculties: | Fakultät für Chemie und Pharmazie / Institut für Anorganische Chemie |
Fakultät für Chemie und Pharmazie / Institut für Organische Chemie | |
Language: | English |
Parent Title (English): | Beilstein Journal of Organic Chemistry |
Year of Completion: | 2017 |
Volume: | 13 |
Pagenumber: | 1-9 |
Source: | Beilstein Journal of Organic Chemistry (2017) 13, 1-9. https://doi.org/10.3762/bjoc.13.1 |
DOI: | https://doi.org/10.3762/bjoc.13.1 |
Pubmed Id: | https://pubmed.ncbi.nlm.nih.gov/28179942 |
Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
Tag: | chemistry; fullerenes; hexakisadducts; hydrogen bonding; porous materials; structure elucidation |
Release Date: | 2021/02/11 |
Licence (German): | CC BY: Creative-Commons-Lizenz: Namensnennung 4.0 International |