Phosphine-Stabilized Diiododiborenes: Isolable Diborenes with Six Labile Bonds
Please always quote using this URN: urn:nbn:de:bvb:20-opus-178608
- The lability of B=B, B-P and B-halide bonds is combined in the syntheses of the first diiododiborenes. In a series of reactivity tests, these diiododiborenes demonstrate cleavage of all six of their central bonds in different ways, leading to products of B=B hydrogenation and dihalogenation as well as halide exchange.
Author: | Jonas H. Muessig, Melanie Thaler, Rian D. Dewhurst, Valerie Paprocki, Jens Seufert, James D. Mattock, Alfredo Vargas, Holger BraunschweigORCiD |
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URN: | urn:nbn:de:bvb:20-opus-178608 |
Document Type: | Preprint |
Faculties: | Fakultät für Chemie und Pharmazie / Institut für Anorganische Chemie |
Language: | English |
Parent Title (English): | Angewandte Chemie, International Edition |
Year of Completion: | 2019 |
Source: | Angewandte Chemie International Edition 2019, 58, 4405. https://doi.org/10.1002/anie.201814230 |
DOI: | https://doi.org/10.1002/anie.201814230 |
Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 546 Anorganische Chemie |
Tag: | 1,2-additions; boron; iodine; low-valent main-group species; multiple bonding |
Release Date: | 2019/04/02 |
EU-Project number / Contract (GA) number: | 669054 |
OpenAIRE: | OpenAIRE |
Note: | This is the pre-peer reviewed version of the following article: J. H. Muessig, M. Thaler, R. D. Dewhurst, V. Paprocki, J. Seufert, J. D. Mattock, A. Vargas, H. Braunschweig, Angew. Chem. Int. Ed. 2019, 58, 4405, which has been published in final form at https://doi.org/10.1002/anie.201814230. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. |
Licence (German): | Deutsches Urheberrecht |