Mild synthesis of diboryldiborenes by diboration of B–B triple bonds
Please always quote using this URN: urn:nbn:de:bvb:20-opus-186306
- A set of diboryldiborenes are prepared by the mild, catalyst-free, room-temperature diboration of the B–B triple bonds of doubly base-stabilized diborynes. Two of the product diboryldiborenes are found to be air- and water-stable in the solid state, an effect that is attributed to their high crystallinity and extreme insolubility in a wide range of solvents.
Author: | Tobias Brückner, Rian D. Dewhurst, Theresa Dellermann, Marcel Müller, Holger BraunschweigORCiD |
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URN: | urn:nbn:de:bvb:20-opus-186306 |
Document Type: | Journal article |
Faculties: | Fakultät für Chemie und Pharmazie / Institut für Anorganische Chemie |
Language: | English |
Parent Title (English): | Chemical Science |
Year of Completion: | 2019 |
Volume: | 10 |
Pagenumber: | 7375-7378 |
Source: | Chemical Science, 2019,10, 7375-7378. doi: 10.1039/C9SC02544H |
DOI: | https://doi.org/10.1039/C9SC02544H |
Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 546 Anorganische Chemie |
Tag: | boron; diboration; diborenes; diborynes; triple bonds |
Release Date: | 2019/08/26 |
EU-Project number / Contract (GA) number: | 669054 |
OpenAIRE: | OpenAIRE |
Licence (German): | CC BY-NC: Creative-Commons-Lizenz: Namensnennung, Nicht kommerziell |