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2,2′-Bipyridyl as a Redox-Active Borylene Abstraction Agent
Please always quote using this URN: urn:nbn:de:bvb:20-opus-215595
- 2,2′-Bipyridyl is shown to spontaneously abstract a borylene fragment (R–B:) from various hypovalent boron compounds. This process is a redox reaction in which the bipyridine is reduced and becomes a dianionic substituent bound to boron through its two nitrogen atoms. Various transition metal–borylene complexes and diboranes, as a well as a diborene, take part in this reaction. In the latter case, our results show an intriguing example of the homolytic cleavage of a B═B double bond.
Author: | Siyuan Liu, Marc-André Légaré, Jens Seufert, Dominic Prieschl, Anna Rempel, Lukas Englert, Theresa Dellermann, Valerie Paprocki, Andreas Stoy, Holger BraunschweigORCiD |
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URN: | urn:nbn:de:bvb:20-opus-215595 |
Document Type: | Journal article |
Faculties: | Fakultät für Chemie und Pharmazie / Institut für Anorganische Chemie |
Language: | English |
Parent Title (English): | Inorganic Chemistry |
Year of Completion: | 2020 |
Volume: | 59 |
Issue: | 15 |
Pagenumber: | 10866-10873 |
Source: | Inorganic Chemistry 2020, 59, 15, 10866–10873. https://doi.org/10.1021/acs.inorgchem.0c01383 |
DOI: | https://doi.org/10.1021/acs.inorgchem.0c01383 |
Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 546 Anorganische Chemie |
Tag: | Boron; Borylene; Heterocycles; Main-group chemistry |
Release Date: | 2020/11/04 |
EU-Project number / Contract (GA) number: | 669054 |
OpenAIRE: | OpenAIRE |
Note: | This document is the unedited Author’s version of a Submitted Work that was subsequently accepted for publication in Inorganic Chemistry, copyright © American Chemical Society after peer review. To access the final edited and published work see https://doi.org/10.1021/acs.inorgchem.0c01383. |
Licence (German): | Deutsches Urheberrecht |