Synthese und Eigenschaften von (Hydroxy-methyl)diorganylsilanen
Synthesis and Properties of (Hydroxymethyl)diorgaoylsilanes
Please always quote using this URN: urn:nbn:de:bvb:20-opus-63727
- The synthesis of the (hydroxymethyl)diorganylsilanes R\(^1\)R\(^2\)Si(H)CH\(_2\)OH (4a: R\(^1\) = R\(^2\) = CH\(_3\), 2-silaisobutanol; 4b: R\(^1\) = CH\(_3\), R\(^2\) == C\(_6\)H\(_5\); 4c: R\(^1\) == R\(^2\) = C\(_6\)H\(_5\))is achieved bythereactionof R\(^1\)R\(^2\)Si(Cl)CH\(_2\)Cl (2a-c) with AcOH/NEt\(_3\) to R\(^1\)R\(^2\)Si(OAc)CH\(_2\)OAc (Ja-c), followed by treating with LiAlH\(_4\) and hydrolysis.
| Author: | Reinhold Tacke, H. Lange, A. Bentlage |
|---|---|
| URN: | urn:nbn:de:bvb:20-opus-63727 |
| Document Type: | Journal article |
| Faculties: | Fakultät für Chemie und Pharmazie / Institut für Anorganische Chemie |
| Language: | German |
| Year of Completion: | 1982 |
| Source: | In: Chemische Berichte (1982) 115, 3673-3677. |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| GND Keyword: | Anorganische Chemie |
| Release Date: | 2012/02/07 |
| Licence (German): |  Deutsches Urheberrecht |