Crystal structure of μ-1κC:2(\(η^2\))-carbonyl-carbonyl-1κC-chlorido-2κCl-μ-chloridoborylene-1:2\(κ^2\) B:B-[1(\(η^5\))-pentamethylcyclopentadienyl](tricyclohexylphosphane-2κP)iron(II)platinum(II) benzene monosolvate
Please always quote using this URN: urn:nbn:de:bvb:20-opus-120120
- In the molecular structure of the dinuclear title compound \([η^5-(C_5(CH_3)_5)(CO)Fe{(μ-BCl)(μ-CO)}PtCl(P(C_6H_{11})_3)]·C_6H_6\), the two metal atoms, iron(II) and platinum(II), are bridged by one carbonyl (μ-CO) and one chloridoborylene ligand (μ-BCl). The \(Pt^{II}\) atom is additionally bound to a chloride ligand situated trans to the bridging borylene, and a tricyclohexylphosphane ligand \((PCy_3)\) trans to the carbonyl ligand, forming a distorted square-planar structural motif at the \(Pt^{II}\) atom. The \(Fe_{II}\) atom is boundIn the molecular structure of the dinuclear title compound \([η^5-(C_5(CH_3)_5)(CO)Fe{(μ-BCl)(μ-CO)}PtCl(P(C_6H_{11})_3)]·C_6H_6\), the two metal atoms, iron(II) and platinum(II), are bridged by one carbonyl (μ-CO) and one chloridoborylene ligand (μ-BCl). The \(Pt^{II}\) atom is additionally bound to a chloride ligand situated trans to the bridging borylene, and a tricyclohexylphosphane ligand \((PCy_3)\) trans to the carbonyl ligand, forming a distorted square-planar structural motif at the \(Pt^{II}\) atom. The \(Fe_{II}\) atom is bound to a pentamethylcyclopentadienyl ligand \([η^5-C_5(CH_3)_5]\) and one carbonyl ligand (CO), forming a piano-stool structure. Additionally, one benzene solvent molecule is incorporated into the crystal structure, positioned staggered relative to the pentamethylcyclopentadienyl ligand at the \(Fe^{II}\) atom, with a centroid–centroid separation of 3.630 (2) Å.…
Author: | Holger BraunschweigORCiD, T. Kramer |
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URN: | urn:nbn:de:bvb:20-opus-120120 |
Document Type: | Journal article |
Faculties: | Fakultät für Chemie und Pharmazie / Institut für Anorganische Chemie |
Language: | English |
Year of Completion: | 2014 |
Volume: | 70 |
Issue: | 11 |
Pagenumber: | 421-423 |
Source: | Acta Crystallographica (2014) E70, 421-423. DOI: 10.1107/S1600536814023381 |
DOI: | https://doi.org/10.1107/S1600536814023381 |
Pubmed Id: | https://pubmed.ncbi.nlm.nih.gov/PMC4257242 |
Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 548 Kristallografie |
Tag: | borylene; crystal structure; heterodinuclear compound; oxidative addition; platinum |
Release Date: | 2015/12/01 |
Licence (German): | CC BY: Creative-Commons-Lizenz: Namensnennung |