Synthesis of functionalized hydrazines: facile homogeneous (N-heterocyclic carbene)-palladium(0)-catalyzed diboration and silaboration of azobenzenes
Please always quote using this URN: urn:nbn:de:bvb:20-opus-186582
- The bis(N-heterocyclic carbene)(diphenylacetylene)palladium complex Pd(ITMe)\(_2\)(PhCCPh)] (ITMe=1,3,4,5-tetramethylimidazol-2-ylidene) acts as a highly active pre-catalyst in the diboration and silaboration of azobenzenes to synthesize a series of novel functionalized hydrazines. The reactions proceed using commercially available diboranes and silaboranes under mild reaction conditions.
| Author: | Melvyn B. Ansell, George E. Kostakis, Holger BraunschweigORCiD, Oscar Navarro, John Spencer |
|---|---|
| URN: | urn:nbn:de:bvb:20-opus-186582 |
| Document Type: | Journal article |
| Faculties: | Fakultät für Chemie und Pharmazie / Institut für Anorganische Chemie |
| Language: | English |
| Parent Title (English): | Advanced Synthesis & Catalysis |
| Year of Completion: | 2016 |
| Volume: | 358 |
| Issue: | 23 |
| Pagenumber: | 3765-3769 |
| Source: | Advanced Synthesis & Catalysis (2016) 358:23. 3765-4769. https://doi.org/10.1002/adsc.201601106 |
| DOI: | https://doi.org/10.1002/adsc.201601106 |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 546 Anorganische Chemie |
| Tag: | B-B bond; N-heterocyclic carbenes; Palladium-catalyzed silaboration; alkenes; azobenzenes; boron; complexes; crystal-structure; design; dilaboration; mechanism; molecular-structure; palladium; silaboration; terminal alkynes |
| Release Date: | 2020/05/27 |
| Licence (German): |  CC BY: Creative-Commons-Lizenz: Namensnennung 4.0 International |