Überbrückte neungliedrige α,β-ungesättigte Enollactone - Synthese aus 5-Phenyl-1,3,4-oxadiazin-6-on-2-carbonsäure-methylester und Konfigurationsanalyse
Please always quote using this URN: urn:nbn:de:bvb:20-opus-58395
- The γ-oxoketenes, which are formed from oxadiazinone Ja and strained cyclopentene der1vat1ves, are shown to undergo a pericyclic ring enlargement to give the title compounds 2a, 2b, and 5. In the case of 5, two configurations, one having a cis and the other a trans Iactone functionality, are in equilibrium.
| Author: | Manfred Christl, J. Hegmann, H. Reuchlein, K. Peters, E.-M. Peters, H. G. von Schnering |
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| URN: | urn:nbn:de:bvb:20-opus-58395 |
| Document Type: | Journal article |
| Faculties: | Fakultät für Chemie und Pharmazie / Institut für Organische Chemie |
| Language: | German |
| Year of Completion: | 1987 |
| Source: | In: Tetrahedron Letters (1987) 28, 51, 6433-6436. |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| GND Keyword: | Organische Chemie |
| Release Date: | 2011/09/01 |
| Licence (German): |  Deutsches Urheberrecht |