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Improved charge carrier lifetime in planar perovskite solar cells by bromine doping

Please always quote using this URN: urn:nbn:de:bvb:20-opus-147976
  • The charge carrier lifetime is an important parameter in solar cells as it defines, together with the mobility, the diffusion length of the charge carriers, thus directly determining the optimal active layer thickness of a device. Herein, we report on charge carrier lifetime values in bromine doped planar methylammonium lead iodide (MAPbI\(_3\)) solar cells determined by transient photovoltage. The corresponding charge carrier density has been derived from charge carrier extraction. We found increased lifetime values in solar cellsThe charge carrier lifetime is an important parameter in solar cells as it defines, together with the mobility, the diffusion length of the charge carriers, thus directly determining the optimal active layer thickness of a device. Herein, we report on charge carrier lifetime values in bromine doped planar methylammonium lead iodide (MAPbI\(_3\)) solar cells determined by transient photovoltage. The corresponding charge carrier density has been derived from charge carrier extraction. We found increased lifetime values in solar cells incorporating bromine compared to pure MAPbI\(_3\) by a factor of ~2.75 at an illumination intensity corresponding to 1 sun. In the bromine containing solar cells we additionally observe an anomalously high value of extracted charge, which we deduce to originate from mobile ions.show moreshow less

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Metadaten
Author: David Kiermasch, Philipp Rieder, Kristofer Tvingstedt, Andreas Baumann, Vladimir Dyakonov
URN:urn:nbn:de:bvb:20-opus-147976
Document Type:Journal article
Faculties:Fakultät für Physik und Astronomie / Physikalisches Institut
Language:English
Parent Title (English):Scientific Reports
Year of Completion:2016
Volume:6
Pagenumber:39333
Source:Scientific Reports 6 , 39333; doi: 10.1038/srep39333 (2016)
DOI:https://doi.org/10.1038/srep39333
Sonstige beteiligte Institutionen:Bavarian Center for Applied Energy Research e.V. (ZAE Bayern)
Dewey Decimal Classification:6 Technik, Medizin, angewandte Wissenschaften / 62 Ingenieurwissenschaften / 621 Angewandte Physik
Tag:devices for energy harvesting; solar cells
Release Date:2017/06/09
Collections:Open-Access-Publikationsfonds / Förderzeitraum 2016
Licence (German):License LogoCC BY: Creative-Commons-Lizenz: Namensnennung