Simple Solution-Phase Syntheses of Tetrahalodiboranes(4) and their Labile Dimethylsulfide Adducts
Please always quote using this URN: urn:nbn:de:bvb:20-opus-149438
- Convenient, solution-phase syntheses of tetrahalodiboranes(4) B\(_2\)F\(_4\), B\(_2\)Cl\(_4\) and B\(_2\)I\(_4\) are presented herein from common precursor B\(_2\)Br\(_4\). In addition, the dimethylsulfide adducts B\(_2\)Cl\(_4\)(SMe\(_2\))\(_2\) and B\(_2\)Br\(_4\)(SMe\(_2\))\(_2\) are conveniently prepared in one-step syntheses from the commercially-available starting material B\(_2\)(NMe\(_2\))\(_4\). The results provide simple access to the full range of tetrahalodiboranes(4) for the exploration of their untapped synthetic potential.
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| Author: | Merle Arrowsmith, Julian Böhnke, Holger BraunschweigORCiD, Andrea Deißenberger, Rian Dewhurst, William Ewing, Christian Hörl, Jan Mies, Jonas Muessig |
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| URN: | urn:nbn:de:bvb:20-opus-149438 |
| Document Type: | Preprint |
| Faculties: | Fakultät für Chemie und Pharmazie / Institut für Anorganische Chemie |
| Language: | English |
| Parent Title (English): | Chemical Communications |
| Year of Completion: | 2017 |
| Volume: | 53 |
| Pagenumber: | 8265-8267 |
| Source: | Chemical Communications, 2017,53, 8265-8267. DOI: 10.1039/C7CC03148C |
| DOI: | https://doi.org/10.1039/C7CC03148C |
| Sonstige beteiligte Institutionen: | Institute for Sustainable Chemistry & Catalysis with Boron |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 546 Anorganische Chemie |
| Tag: | Boron; Diboranes; Tetrafluorodiborane |
| Release Date: | 2017/08/01 |
| EU-Project number / Contract (GA) number: | 669054 |
| OpenAIRE: | OpenAIRE |
| Note: | This is the pre-peer reviewed version of the following article: Chemical Communications, 2017,53, 8265-8267, which has been published in final form at doi:10.1039/C7CC03148C. |
| Licence (German): |  Deutsches Urheberrecht |