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Mild synthesis of diboryldiborenes by diboration of B–B triple bonds

Please always quote using this URN: urn:nbn:de:bvb:20-opus-186306
  • A set of diboryldiborenes are prepared by the mild, catalyst-free, room-temperature diboration of the B–B triple bonds of doubly base-stabilized diborynes. Two of the product diboryldiborenes are found to be air- and water-stable in the solid state, an effect that is attributed to their high crystallinity and extreme insolubility in a wide range of solvents.

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Author: Tobias Brückner, Rian D. Dewhurst, Theresa Dellermann, Marcel Müller, Holger Braunschweig
Document Type:Journal article
Faculties:Fakultät für Chemie und Pharmazie / Institut für Anorganische Chemie
Parent Title (English):Chemical Science
Year of Completion:2019
Source:Chemical Science, 2019,10, 7375-7378. doi: 10.1039/C9SC02544H
Dewey Decimal Classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 546 Anorganische Chemie
Tag:boron; diboration; diborenes; diborynes; triple bonds
Release Date:2019/08/26
EU-Project number / Contract (GA) number:669054
Licence (German):License LogoCC BY-NC: Creative-Commons-Lizenz: Namensnennung, Nicht kommerziell