CO\(_2\) Binding and Splitting by Boron–Boron Multiple Bonds
Please always quote using this URN: urn:nbn:de:bvb:20-opus-164265
- CO\(_2\) is found to undergo room-temperature, ambient- pressure reactions with two species containing boron-boron multiple bonds, leading to incorporation of either one or two CO\(_2\) molecules. In one case, a thermally-unstable intermediate was structurally characterized, indicating the operation of an initial 2+2 cycloaddition mechanism in the reaction.
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| Author: | Andreas Stoy, Julian Böhnke, J. Oscar C. Jiménez-Halla, Rian D. Dewhurst, Torsten Thiess, Holger BraunschweigORCiD |
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| URN: | urn:nbn:de:bvb:20-opus-164265 |
| Document Type: | Preprint |
| Faculties: | Fakultät für Chemie und Pharmazie / Institut für Anorganische Chemie |
| Language: | English |
| Parent Title (English): | Angewandte Chemie, International Edition |
| Year of Completion: | 2018 |
| Source: | Angewandte Chemie International Edition 2018, 57,5947–5951. DOI:10.1002/anie.201802117 |
| DOI: | https://doi.org/10.1002/anie.201802117 |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 546 Anorganische Chemie |
| Tag: | CO2 fixation; boron; carbon dioxide; diborenes; diborynes |
| Release Date: | 2018/07/24 |
| EU-Project number / Contract (GA) number: | 669054 |
| OpenAIRE: | OpenAIRE |
| Note: | This is the pre-peer reviewed version of the following article: A. Stoy, J. Böhnke, J. O. C. Jiménez‐Halla, R. D. Dewhurst, T. Thiess, H. Braunschweig, Angew. Chem. Int.Ed. 2018, 57,5947 –5951, which has been published in final form at DOI: 10.1002/anie.201802117. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. |
| Licence (German): |  Deutsches Urheberrecht |