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Phosphine-Stabilized Diiododiborenes: Isolable Diborenes with Six Labile Bonds

Please always quote using this URN: urn:nbn:de:bvb:20-opus-178608
  • The lability of B=B, B-P and B-halide bonds is combined in the syntheses of the first diiododiborenes. In a series of reactivity tests, these diiododiborenes demonstrate cleavage of all six of their central bonds in different ways, leading to products of B=B hydrogenation and dihalogenation as well as halide exchange.

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Author: Jonas H. Muessig, Melanie Thaler, Rian D. Dewhurst, Valerie Paprocki, Jens Seufert, James D. Mattock, Alfredo Vargas, Holger Braunschweig
Document Type:Preprint
Faculties:Fakultät für Chemie und Pharmazie / Institut für Anorganische Chemie
Parent Title (English):Angewandte Chemie, International Edition
Year of Completion:2019
Source:Angewandte Chemie International Edition 2019, 58, 4405. https://doi.org/10.1002/anie.201814230
Dewey Decimal Classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 546 Anorganische Chemie
Tag:1,2-additions; boron; iodine; low-valent main-group species; multiple bonding
Release Date:2019/04/02
EU-Project number / Contract (GA) number:669054
This is the pre-peer reviewed version of the following article: J. H. Muessig, M. Thaler, R. D. Dewhurst, V. Paprocki, J. Seufert, J. D. Mattock, A. Vargas, H. Braunschweig, Angew. Chem. Int. Ed. 2019, 58, 4405, which has been published in final form at https://doi.org/10.1002/anie.201814230. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
Licence (German):License LogoDeutsches Urheberrecht