Highly colored boron-doped thiazolothiazoles from the reductive dimerization of boron isothiocyanates
Please always quote using this URN: urn:nbn:de:bvb:20-opus-256432
- Reduction of (CAAC)BBr\(_2\)(NCS) (CAAC=cyclic alkyl(amino)carbene) in the presence of a Lewis base L yields tricoordinate (CAAC)LB(NCS) borylenes which undergo reversible E/Z-isomerization. The same reduction in the absence of L yields deep blue, bis(CAAC)-stabilized, boron-doped, aromatic thiazolothiazoles resulting from the dimerization of dicoordinate (CAAC)B(NCS) borylene intermediates.
| Author: | Stephan Hagspiel, Merle Arrowsmith, Felipe Fantuzzi, Alfredo Vargas, Anna Rempel, Alexander Hermann, Tobias Brückner, Holger BraunschweigORCiD |
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| URN: | urn:nbn:de:bvb:20-opus-256432 |
| Document Type: | Journal article |
| Faculties: | Fakultät für Chemie und Pharmazie / Institut für Anorganische Chemie |
| Language: | English |
| Parent Title (English): | Angewandte Chemie International Edition |
| Year of Completion: | 2021 |
| Volume: | 60 |
| Issue: | 12 |
| Pagenumber: | 6446-6450 |
| Source: | Angewandte Chemie International Edition (2021) 60:12, 6446-6450. DOI: 0.1002/anie.202015508 |
| DOI: | https://doi.org/10.1002/anie.202015508 |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 546 Anorganische Chemie |
| Tag: | DFT; aromaticity; borylenes; fused thiazaboroles; inorganic chemistry; reduction |
| Release Date: | 2022/02/22 |
| Licence (German): |  CC BY-NC: Creative-Commons-Lizenz: Namensnennung, Nicht kommerziell 4.0 International |